SURFACE COVERAGE CONTAINING GAS, STRUCTURE AND USE OF THIS

专利摘要:
surface covering containing gas, structure and use thereof. one aspect of the invention relates to a surface cover for a body that can be placed in contact with a liquid, which comprises: a layer that contains gas at least in part and that is designed and arranged so that at least some sections of one side of the layer facing the liquid come into contact with the liquid; a gas-permeable tarpaulin, which is disposed in the gas retention layer on a face facing the body opposite the face facing the liquid or which is integrally formed with the gas retention layer; and a gas supply device, which connects to the gas permeable tarp so that gas flows from the gas supply device to the gas retaining layer through the gas permeable tarp. the invention also relates to structure and use.
公开号:BR112014021810B1
申请号:R112014021810-2
申请日:2013-02-22
公开日:2020-12-15
发明作者:Thomas Schimmel
申请人:Baden-Württemberg Stiftung Ggmbh；
IPC主号:

专利说明:

[0001] The present invention relates to a gas-retained surface cover for a body that can be placed in contact with a liquid, its corresponding structure and its use.
[0002] In nature, there is knowledge of plant and animal surfaces that, when submerged in water, are little moistened by water because air is retained in the surface structure, which makes the submerged parts of the plant or animal not to be moistened by water. These surfaces can be found, among others, in floating aquatic ferns (for example, Salvinia molesta) or in aquatic insects (for example, Notonecta glauca). With the help of air trapped on the surface with layer thicknesses from about 1 μm to about 1 mm, floating aquatic macrophytes, for example, can increase their buoyancy, and aquatic insects can use the air supply loaded with them under of water to breathe.
[0003] However, the air escapes because of the separation of the gas bubbles and as a result of the dissolution of the air in the liquid surrounding the layer of air retained on the surface of the plant or animal to the surrounding water, such that the layer of air runs out over time. Since the immersion time of an aquatic insect and the leaf of a vital floating aquatic macrophyte is, however, shorter than the time required to consume the air layer, the dissolution of gases from the air layer in the surrounding water does not it's a problem.
[0004] In technical applications, however, there is a problem of permanently separating the surface of a submerged body from the surrounding liquid by means of a layer of water.
[0005] This problem is solved through the topics of the independent claims. The dependent claims refer to preferred embodiments. Use according to aspect
[0006] One aspect refers to the use of a gas retention layer designed and arranged in a body, which can be submerged in liquid in order to make contact, at least regionally through a side facing the liquid, with the liquid when the body is submerged, at least regionally, in the liquid, where a layer of gas retained in the submerged region of the gas retention layer separates the liquid and the submerged region of the body from each other at least regionally.
[0007] It is advantageously possible, thanks to the gas retaining layer, to retain a substantially constant volume of gas in the body for a predetermined period of time, in particular arbitrary, so that the body can be separated from the surrounding liquid by the layer holding gas or by the gas trapped in said layer. In particular, the body is thus advantageously protected against corrosive liquids. In addition, it is advantageously possible to decrease the resistance to the flow of the body in the case of relative movement between the body and the liquid.
[0008] In the context of this application, the body can be any solid body that can be submerged, at least regionally, in liquid. In other words, the body, when submerged in the liquid, cannot dissolve in that liquid and is not destroyed by the acting liquid pressure. In this case, the liquid pressure can, on the one hand, act from the outside towards the body's center of gravity, if the body is submerged in the liquid, and, on the other hand, can act from the inside, if the liquid fills a cavity of the body. body. Exemplary bodies in the context of this application include ships, buoys, pontoons, conduits, pipes, underwater cables, oil drilling platforms, gas drilling platforms, foundations and parts exposed to water in marine facilities (in particular wind farms for electricity generation ), underwater structures, underwater installations, liquid-exposed measuring equipment, coastal structures, vessels and ducts for liquids or parts thereof. Preferably, the body comprises a substantially rigid wall that is subjected to liquid pressure. Particularly preferably, the body wall is resilient, in particular of an elastically deformable nature.
[0009] The liquid, which can surround the body at least regionally or fill it at least regionally, is especially water (either fresh or salt water) or an aqueous solution, although the liquid can also comprise alcohols, alkanes, oils , polar and nonpolar solvents and other organic and inorganic liquids.
[0010] The gas retention layer can be used to form or cover a face or surface of the body in whole or in part. In this case, the gas retaining layer can be detachably attached or not to the body. The surface covering may preferably be in the form of a coating on the body. After attaching the gas retention layer to the body, it can form the body surface at least regionally or be considered part of the body. In particular, the gas retention layer attaches to the body so that liquid does not pass between the gas retention layer and the body.
[0011] The gas retention layer has one side facing the liquid and one side facing the body. The gas retention layer is designed so that, during the operational use of the body, the gas in the gas retention layer remains in contact with it, where, thanks to the gas, the liquid-facing side of the gas layer Gas retention is at least in part, preferably entirely, separated from the surface or contact interface between the retained gas and the liquid (liquid-gas interface). The gas, which is retained in the gas retention layer, in the context of this application, is not part of the gas retention layer or the body, but part of a gas containment layer comprising the gas retention layer and the gas trapped in it. In other words, said retained gas is fixed by the gas retention layer so that, advantageously, it does not rise to the surface of the liquid and is not carried away by the liquid flow.
[0012] The gas retention layer may have a base or base tarpaulin which preferably has structural elements such as protrusions, protruding elements and / or recesses which are, in part, designed to retain gas and which are preferably formed entirely at the base. The base can be in mesh format or in the form of a closed tarpaulin.
[0013] The gas retention layer, correspondingly, also has a contact surface between the gas contained in the gas retention layer and a solid material. The liquid-facing or gas-facing side of the gas retaining layer is preferably hydrophobic in nature or can be coated with hydrophobic material. In the context of the present invention, the term "hydrophobic" means the same as "liquid repellent", that is, "liquidophobic". The term "hydrophobic" duly indicates that the liquid is water or an aqueous solution or, in general, a polar solvent. However, it is evident that the choice of the liquid with which contact is made is fundamental. If the liquid to be contacted is, for example, an alkane, the term "hydrophobic" can also be understood as "alkanophobic".
[0014] It is possible to determine whether a surface or material is liquid-repellent based on the angle of contact of a liquid droplet with a surface of the material. The magnitude of the contact angle between the liquid and the solid, in this case, depends on the interaction between the liquid and the solid on the contact surface. The weaker the interaction, the greater the contact angle. Hydrophilic solids have contact angles of about 0 ° to about 90 °, in particular contact angles less than about 80 °, with the surface of the liquid, especially with water. Contact angles of about 90 ° and greater occur in the case of hydrophobic solids. Solids with a contact angle considerably greater than 90 °, in particular contact angles of about 160 ° and greater, with liquid, especially with water, are called super-hydrophobes. The term "hydrophobic", therefore, also encompasses the preferred case in which the material is "super-hydrophobic".
[0015] The subject of study of the present invention refers, in particular, to the coexistence of regions and / or hydrophilic and hydrophobic elements. In the context of the invention, therefore, it happens that a first element is distinguished as hydrophobic from a second, hydrophilic, even though both are classified as hydrophobic or hydrophilic according to the absolute criteria described above with reference to the angle of contact with the liquid, but the first element is more hydrophobic than the second. In other words, the relatively hydrophobic element or the relatively hydrophobic region is called hydrophobic, and the relatively hydrophilic element, that is, less hydrophobic, or the relatively hydrophilic regions are called hydrophilic. In other words, in the context of the invention, the terms hydrophobic and hydrophilic can describe a relative hydrophobia or a contrast in hydrophobia.
[0016] During operational use, the gas retention layer can be supplied, for example, with air, carbon dioxide or some other gas.
[0017] The gas retention layer preferably has recesses and / or depressions at least regionally on the side facing the liquid. The surface of the gas-retaining layer may preferably be hydrophobic in the region of the recesses and / or depressions. For example, the gas retaining layer can be made of hydrophobic material. Alternatively, the gas retaining layer may comprise a hydrophilic material provided with a hydrophobic coating regionally. In particular, the hydrophobic coating can be formed only on the walls of the recesses or depressions. Particularly preferably, the gas retention layer is composed at least regionally of porous material, in which the recesses or depressions are formed by pores connected to the surface.
[0018] Preferably, the gas retention layer has protrusions or protruding elements at least regionally on the side facing the liquid, where the surface of the gas retention layer is substantially hydrophobic in the region of the protrusions or protruding elements. The spacing between the protruding elements is sized appropriately so that no liquid droplets are deposited between the protruding elements. The different liquid droplets are advantageously supported by several protruding elements, so that the interface between liquid and gas located between the protruding elements is substantially in the form of a wrap of the protruding elements. In particular, the spacing between two adjacent protruding elements can be from about 50 μm to about 500 μm, preferably from about 100 μm to about 200 μm.
[0019] Preferably, the protrusions or protruding elements have a region of central hydrophilic surface surrounded by a region of hydrophobic surface thereof. The interface between liquid and gas is advantageously located in regions of a hydrophilic nature. In this way, the separation of gas bubbles by the liquid flow is more advantageously prevented.
[0020] Preferably, the gas retention layer is divided into several sub-regions (also called "compartments") by means of fluid impermeable partitions. Preferably, the partitions (42) are at least regionally or entirely hydrophilic in nature or at least regionally or entirely equipped with a hydrophilic surface. Fluid should be interpreted as a gas, a liquid or a mixture of both. Therefore, the partition prevents the flow of liquid or the flow of gas between adjacent subregions. It advantageously happens that, in the presence of a pressure differential between two adjacent sub-regions, the partitions prevent the gas from flowing from one sub-region to another and, as a result, the resistance to flow in relation to the liquid with which it is made. contact increases locally and, in contrast, excessive gas is released into the liquid from the sub-region to which the gas flows.
[0021] Preferably, the partitions are built in one piece or integrally with other elements of the gas retention layer. It is also preferable that several hydrophobic protruding elements are located in a two-dimensional arrangement in all subregions of the gas retention layer.
[0022] Preferably, the gas retention layer comprises an embossed plastic resin or an embossed lacquer. In particular, the gas retention layer can be molded from a liquid plastic resin, where, preferably, protruding elements are formed integrally or in one piece together with a base canvas of the gas retention layer and / or with gas-permeable tarpaulin. In particular, the base tarpaulin of the gas retaining layer may be identical to the gas permeable tarpaulin. Particularly preferably, the gas retention layer is formed, with the plastic resin or the lacquer, indirectly or directly on the immersible body wall. In particular, the gas retaining layer can be used to build a surface coating or surface seal on the body.
[0023] Preferably, the gas retention layer is coated at least regionally with polytetrafluoroethylene (PTFE), also known by the trade name Teflon, or derivatives thereof. In particular, the coating can also comprise microparticles or nanoparticles of polytetrafluoroethylene or other materials. The coating made of PTFE advantageously acts as a hydrophobic layer and as an anti-adhesion agent, in order to prevent the adhesion of liquids or solids to the gas retention layer. The coating of the gas retention layer is preferably from about 0.15 nm to about 500 nm in thickness.
[0024] The liquid is preferably water, and the body is preferably a vessel whose wall is submerged, at least regionally, in the water when the vessel is in an operating position.
[0025] It is advantageously the case that water, in particular sea water, at least regionally does not wet the vessel's wall, so that the vessel is protected against the influence of water. The vessel can, for example, be a ship, a drilling rig or a buoy. The influence of water refers, in particular, to the corrosion of the vessel wall. Sea water or brackish water, in particular, promote corrosion of the vessel wall because of the salt content. As the contact between the water and the vessel wall is prevented by the interposed gas, which is retained in the gas retention layer, corrosion also decreases.
[0026] Another advantage is that the vessel's wall is not encrusted with organisms that live in the water, for example, algae, mussels, barnacles and others. The gas layer makes it difficult for these organisms to attach themselves to the vessel wall. In other words, the surface cover according to the present invention has an anti-fouling action advantageously possible to dispense with the use of biocides, poisonous substances that dissolve in water over time. Thanks to the lower adhesion of organisms to the vessel wall, the vessel's flow resistance also decreases.
[0027] It is preferably the case that, between the gas retention layer, a gas is loaded at least regionally in order to decrease the resistance to the flow between the water and the vessel. In particular, the gas layer can be from about 10 nm to about 10 mm thick, preferably from about 500 nm to about 3 mm, in particular from about 0.1 mm to about 3 mm. If the gas layer is intended to serve merely for corrosion prevention, even a relatively thin gas layer with a thickness of about 5 nm to about 3 mm, preferably from about 50 nm to about 1 nm , especially from about 100 nm to about 100 μm, it is enough to obtain the corrosion prevention action. As the gas layer disconnects the vessel's wall from flowing water, and in particular, the contact surface between the gas and the water can be deformed by the flow, thus forming an extremely functional contact surface, the vessel's flow resistance as it passes through the water it decreases advantageously. In particular, the vessel's fuel consumption advantageously decreases thanks to the lower resistance to the flow between the vessel and the water.
[0028] A corrosion-preventing coating and / or an anti-fouling coating is preferably disposed between the gas-retaining layer and the vessel wall, where the gas-retaining layer separates the water-preventing coating corrosion and / or anti-fouling water coating at least regionally.
[0029] The corrosion prevention coating, in general, takes the form of a layer of paint on the vessel's wall and may contain poisonous substances, such as heavy metals. The dissolution of these poisonous substances in water from the corrosion prevention coating is reduced or prevented by the arrangement of the gas retention layer between the corrosion prevention coating and the water. This avoids contamination of water, especially sea water, with poisonous substances. In particular, heavy metals are prevented from passing a layer of corrosion prevention paint into the water and accumulating in the food chain.
[0030] As an alternative, or in addition, an anti-fouling coating is formed on the vessel wall, for example, in the form of a layer of paint on the wall. The anti-fouling coating, in general, includes biocides, that is, poisonous substances lethal to organisms that adhere to the vessel wall. The dissolution of these poisonous substances in water from the antifouling coating is reduced or prevented by the arrangement of the gas retention layer between the antifouling coating and the water. Thus, water contamination, especially sea water, with biocides is advantageously avoided. In particular, biocides are prevented from harming or exterminating organisms that live in the water, such as plankton, which would disrupt the food chain in the water.
[0031] Preferably, the gas retention layer is fed with a scale-inhibiting gas. The fouling inhibitory gas may contain, for example, carbon dioxide, so that the organisms that have accumulated on the vessel wall are deprived of oxygen or saturated with carbon dioxide. These organisms therefore die without the need to use a toxic substance in the anti-fouling coating. This advantageously leads to less contamination of the water with poisonous substances.
[0032] Preferably, the body is a vessel wall that can be wetted with a liquid and on whose wall the gas retention layer is arranged at least regionally.
[0033] It is advantageously the case that the liquid at least regionally does not wet the vessel wall, so that the vessel wall is protected against the influence of the liquid. The vessel with the vessel wall can, for example, be a tank, conduit, reactor or the like. The influence of the liquid refers, in particular, to corrosion of the vessel wall, the chemical reaction of the liquid with the vessel wall or the mechanical loading of the vessel wall with particles contained in the liquid. Corrosion of the vessel wall is promoted, in particular, by salty, brine or acid solutions. As the contact between the liquid and the vessel wall is prevented by the gas disposed between them and retained in the gas retention layer, corrosion also decreases.
[0034] Particularly preferably, the vessel wall comprises a sensing window in which a gas retention layer is arranged. The detection of data by sensor can be advantageously improved because no deposit, for example, of particles or organisms, accumulates in the sensing window. In particular, the sensing window and / or the gas retention layer are optically transparent.
[0035] A corrosion prevention coating is preferably disposed between the gas retaining layer and the vessel wall, where the gas retaining layer separates the corrosion preventing coating from the liquid at least regionally.
[0036] The corrosion prevention coating, in general, is in the form of a layer of paint on the vessel wall or is formed by galvanizing or anodizing, and may contain poisonous substances such as heavy metals. The dissolution of these poisonous substances in the liquid from the corrosion prevention coating is reduced or prevented by the arrangement of the gas retention layer between the corrosion protection coating and the liquid. Thus, the contamination of the liquid is advantageously avoided, especially with poisonous substances. In particular, said corrosion prevention coating substances are prevented from influencing a chemical reaction within the vessel.
[0037] Preferably, the gas retaining layer is supplied with gas from the side facing the body, located opposite the liquid facing side of the gas retaining layer.
[0038] Preferably, a gas-permeable tarp is disposed on the side facing the body in the gas retention layer. In other words, the gas-permeable tarpaulin can be arranged and / or attached to the side facing the body of the gas retaining layer. Alternatively, the gas-permeable tarpaulin may also be constructed of a piece integral with the gas retention layer or it may be an integral part of the gas retention layer. Gas can be fed to the gas holding layer through the liquid-facing side of the gas-permeable tarp, which can make contact with the side facing the body of the gas holding layer. In other words, the gas-permeable tarpaulin may be gas-permeable, especially in a direction perpendicular to the side facing the body of the gas retaining layer.
[0039] The gas-permeable tarpaulin is preferably in the form of a liquid impervious tarpaulin and / or hydrophobic tarpaulin. Advantageously, the liquid does not flow through the gas permeable tarpaulin towards the body, for example, even though the pressure of the liquid is temporarily greater than the gas pressure in the gas permeable tarpaulin. In other words, the gas-permeable tarpaulin repels water and other polar solvents, whereby said polar solvents are advantageously prevented from entering the gas-permeable tarpaulin.
[0040] Preferably, a gas supply device connects to the gas permeable tarpaulin so that gas flows from the gas supply device to the gas retaining layer through the gas permeable tarpaulin.
[0041] It is advantageously possible to feed gas to the gas retaining layer through the gas supply device through the gas permeable tarp. In particular, it is possible to feed at least the amount of gas that escapes from the gas retaining layer to the surrounding liquid. Thus, it is advantageously possible to maintain a substantially constant volume of gas within the gas retention layer for any desired period of time, whereby the body and the surrounding liquid can be permanently separated by the gas in the gas retention layer.
[0042] The gas can be supplied by the gas supply device, which connects to the gas-permeable tarpaulin. Preferably, the gas supply device is a canvas of porous material with a continuous porous space, such that gas flows from the gas supply device to the gas retaining layer through the gas permeable canvas.
[0043] Preferably, the gas-permeable canvas comprises a woven or non-woven textile, a woolen material, a porous ceramic, a porous metal, a felt composed of polymeric or metallic fibers and / or a metallic fabric. The gas-permeable tarpaulin can, for example, be woven with polymeric fibers or made with a felt or non-woven fabric composed of polymeric fibers. A gas-permeable tarp made of a polymer can attach to the gas-retaining layer, especially by lamination. As an alternative, or in addition, the gas-permeable tarpaulin may comprise a fabric composed of metallic threads, in particular corrosion resistant metallic threads, for example, high-grade rust resistant steel threads, with which a high level of resistance mechanical wear, resistance to UV radiation and chemical influences is advantageously obtained. Alternatively, the gas-permeable tarpaulin may also comprise a wool material, for example, polymer wool or elastomer wool, composed in particular of a foamed material. Thus, the weight of the gas-permeable tarpaulin is advantageously reduced. In addition, a gas-permeable tarpaulin preferably comprises a sintered material, such as, for example, a porous sintered material composed of metallic particles. Preferably, the gas-permeable tarpaulin is connected to the gas retaining layer by means of an adhesive. Alternatively, the gas retaining layer and the gas permeable tarpaulin are connected to each other by welding, in particular by ultrasonic welding (ultrasonic welding). Preferably, the gas-retaining layer and the gas-permeable tarpaulin are formed in one piece with each other, for example, from a polymer by means of a (continuous) molding or casting process.
[0044] Preferably, the gas-permeable tarpaulin is in the form of a porous semipermeable membrane. The gas-permeable tarpaulin is in particular in the form of a gas-permeable metallic foil made of a polymer. Gas-permeable metal sheets can, for example, have a thickness of about 0.5 μm to 5 μm. Thus, it is possible to provide a thin and light surface coverage. In particular, metal sheets made of polymer can connect to the gas-retaining layer by lamination.
[0045] Preferably, the gas supply device is in the form of a gas-permeable layer disposed on the side facing the body of the gas-permeable layer. In particular, the gas supply device also comprises a porous material with continuous pores. The gas permeability through the gas supply device is suitably higher than the gas permeability through the gas permeable tarpaulin.
[0046] Preferably, the gas supply device is in the form of an aerenchyma. An aerenchyma is an air passage structure in aquatic plants that allows the transport and storage of gas. In particular, the term “aerenchyma” is understood as a form of basic plant structure in which the intercellular spaces are large enough to form a true “air passage structure.” It is found, especially in plants swamp and aquatic plants and serves for the gas exchange of the plant's submerged organs.
[0047] In other words, the gas supply device is in the form of a gas tank, so that, with increasing liquid pressure, the gas is displaced through the gas permeable tarp back to the gas supply device. gas and stored there so that it is moved to the gas retention layer again through the gas permeable tarpaulin in case of reduction of the liquid pressure. The gas supply device may, for example, have a porous material where the gas is stored. In addition, the material can be resiliently expandable, so that the volume increases as the gas pressure increases and the gas is forced through the gas-permeable tarp to the gas retention layer thanks to the resilient force of the material. It is also preferable that the internal walls of the gas supply device, which make contact with the gas, are at least regionally hydrophobic in nature. It is advantageously possible for the gas in the gas retaining layer to be temporarily stored in the gas supply device, instead of being released from the gas retaining layer, in the event of fluctuations in the liquid pressure.
[0048] Preferably, the gas retention layer is supplied with gas from the liquid-facing side of the gas retention layer.
[0049] It is preferable to include at least one gas discharge device with a gas discharge opening on the liquid-facing side of the gas retaining layer, in which a gas supply device is connected which connects to the gas discharge device. gas discharge, wherein the gas fed by the gas supply device leaves the gas discharge device and is at least partly received in the gas retaining layer.
[0050] Preferably, the gas discharge device extends through the gas retaining layer. In other words, a gas discharge opening for the gas holding device is formed on the liquid side of the gas holding layer.
[0051] Preferably, the gas supply device is in the form of a gas-permeable layer disposed on the side facing the body of the gas-permeable layer. Particularly preferably, the gas supply device is in the form of an aerenchyma. For greater advantage, the gas supply device easily and fluidly connects to various gas discharge devices, where the gas discharge devices can, in particular, be arranged evenly or irregularly over an area. Vessel according to an aspect
[0052] One aspect refers to a vessel that has: - a wall submerged at least regionally in water when the vessel is in an operational position, in which a gas retention layer is arranged at least in part on the side facing the water; and which has: - a gas-permeable tarp arranged on one side facing the wall, located opposite the side facing the water, between the gas retaining layer and the wall; - a gas supply device, which connects to the gas permeable tarp so that gas flows from the gas supply device to the gas retaining layer through the gas permeable tarp, or which has: - at least one gas discharge device, which has a gas discharge opening on the water-facing side of the gas retention layer; - a gas supply device, which connects to the gas discharge device, in which the gas fed by the gas supply device leaves the gas discharge device and is received at least in part in the gas retention layer .
[0053] Preferably, a corrosion prevention coating and / or an anti-fouling coating is disposed between the gas retaining layer and the vessel wall, where the gas retaining layer separates the corrosion preventing coating and / or the anti-fouling coating of the water at least regionally.
[0054] Preferably, the gas retaining layer is fed with a scale-inhibiting gas.
[0055] One aspect refers to a liquid vessel comprising: - a vessel wall that can be wetted at least regionally with a liquid, in which a retention layer at least in part of the gas is arranged on a side facing for the liquid in the vessel wall; and which comprises: - a gas-permeable tarpaulin arranged on one side facing the wall, located opposite the side facing the water, between the gas retaining layer and the vessel wall; and - a gas supply device, which connects to the gas permeable tarp so that gas flows from the gas supply device to the gas retaining layer through the gas permeable tarp, or which comprises: - at least a gas discharge device, which has a gas discharge opening on the liquid side of the gas retaining layer; and - a gas supply device, which connects to the gas discharge device, in which the gas fed by the gas supply device leaves the gas discharge device and is received at least in part in the gas retention layer gas.
[0056] Preferably, a corrosion prevention coating is disposed between the gas retaining layer and the liquid vessel wall, wherein the gas retaining layer separates the corrosion preventing coating from the liquid at least regionally.
[0057] Surface coverage according to an aspect
[0058] One aspect refers to a surface cover for a body that can be placed in contact with a liquid, which comprises: - a retention layer at least part of the gas, which is designed and arranged to make contact, at least regionally through a side facing the liquid, with the liquid; - a gas-permeable tarpaulin, which is arranged on one side facing the body, located opposite the side facing the liquid, in the gas retention layer or which is formed integrally with the gas retention layer; - a gas supply device, which connects to the gas permeable tarp so that gas flows from the gas supply device to the gas retaining layer through the gas permeable tarp.
[0059] It is advantageously possible to feed gas to the gas retaining layer through the gas supply device through the gas permeable tarpaulin. In particular, it is possible to feed at least the amount of gas that escapes from the gas retaining layer to the surrounding liquid. Thus, it is advantageously possible to maintain a substantially constant volume of gas within the gas retention layer for any desired period of time, whereby the body and the surrounding liquid can be permanently separated by the gas in the gas retention layer. In particular, the body is thus advantageously protected against corrosive liquids. In addition, it is advantageously possible to decrease the resistance to the flow of the body in the case of relative movement between the body and the liquid.
[0060] In the context of this application, the body that can be placed in contact with the liquid can be any solid body that can be submerged, at least regionally, in liquid. In other words, the body, when submerged in the liquid, does not dissolve in that liquid and is not destroyed by the active liquid pressure. In this case, the liquid pressure can, on the one hand, act from the outside towards the body's center of gravity, if the body is submerged in the liquid, and, on the other hand, can act from the inside, if the liquid fills a cavity of the body. body. Exemplary bodies in the context of this application include ships, buoys, pontoons, coastal structures, vessels and ducts for liquids. Preferably, the body comprises a substantially rigid wall that is subjected to liquid pressure. Particularly preferably, the body wall is resilient, in particular of an elastically deformable nature.
[0061] In the context of the present invention, the term "resilient" means, in particular, that the body wall can be deformed by the action of an external force, such as, for example, the liquid pressure, in which the deformation is reversed substantially completely when the external force ceases to act, that is, the body substantially returns to its original shape or position after the external force has acted.
[0062] The liquid, which can surround the body at least regionally or which can fill the body can comprise, in particular, water (be it fresh or salt water) and aqueous solutions, but also alcohols, alkanes, oils, polar and nonpolar solvents and other organic and inorganic liquids.
[0063] The surface cover can cover all or part of a face or surface of the body. In addition, the surface cover can be detachable or not attached to the body. In particular, the surface covering may be in the form of a coating on the body. After attaching the surface cover to the body, it can be considered part of the body.
[0064] The at least partial gas retention layer has one side facing the liquid and one side facing the body. The gas retaining layer is designed so that, during the operational use of the body or surface cover, the gas in the gas retaining layer remains in contact with it, where, thanks to the gas, the side facing the liquid in the gas retention layer is at least partly, preferably entirely, separated from the surface or contact interface between the retained gas and the liquid (liquid-gas interface). The gas, which is retained in the gas retention layer, in the context of this application, is not part of the gas retention layer or the surface cover, but part of a gas containment layer comprising the gas retention layer and the gas trapped in it. In other words, said retained gas is fixed by the gas retention layer so that, advantageously, it does not rise to the surface of the liquid and is not carried away by the liquid flow.
[0065] The gas retention layer may have a base or base canvas that preferably has structural elements such as protrusions, protruding elements and / or recesses that are, in part, designed to retain gas and which are preferably formed entirely at the base. The base can be in mesh format or in the form of a closed canvas.
[0066] The gas retention layer, correspondingly, also has a contact surface between the gas contained in the layer and a solid material. The liquid-facing side or the gas-facing side of the gas retaining layer is hydrophobic in nature or can be coated with hydrophobic material. In the context of the present invention, the term "hydrophobic" means the same as "liquid repellent", that is, "liquidophobic". The term "hydrophobic" duly indicates that the liquid is water or an aqueous solution or, in general, a polar solvent. However, it is evident that the choice of the liquid with which contact is made is fundamental. If the liquid to be contacted is, for example, an alkane, the term "hydrophobic" can also be understood as "alkanophobic".
[0067] It is possible to determine whether a surface or material is liquid-repellent based on the angle of contact of a liquid droplet with a surface of the material. The magnitude of the contact angle between the liquid and the solid, in this case, depends on the interaction between the liquid and the solid on the contact surface. The weaker the interaction, the greater the contact angle. Hydrophilic solids have contact angles of about 0 ° to about 90 °, in particular contact angles less than about 80 °, with the surface of the liquid, especially with water. Contact angles of about 90 ° and greater occur in the case of hydrophobic solids. Solids with a contact angle considerably greater than 90 °, in particular contact angles of about 160 ° and greater, with liquid, especially with water, are called super-hydrophobes. The term "hydrophobic", therefore, also encompasses the preferred case in which the material is "super-hydrophobic".
[0068] The gas-permeable tarpaulin is arranged and / or attached to the side facing the body of the gas retention layer. Alternatively, the gas-permeable tarpaulin may also be constructed of a piece integral with the gas retention layer or it may be an integral part of the gas retention layer. Gas can be fed to the gas holding layer through the liquid-facing side of the gas-permeable tarp, which can make contact with the side facing the body of the gas holding layer. In other words, the gas-permeable tarpaulin is permeable to a gas, especially in a direction perpendicular to the side facing the body of the gas retaining layer.
[0069] The gas fed to the gas retention layer can, for example, be air, carbon dioxide or some other gas. The gas can be supplied by the gas supply device, which connects to the gas-permeable tarpaulin. Preferably, the gas supply device is a canvas of porous material with a continuous porous space, such that gas flows from the gas supply device to the gas retaining layer through the gas permeable canvas.
[0070] Preferably, the gas-permeable tarpaulin is impermeable to liquid, in particular impermeable to water or impervious to liquid. It is advantageously possible for gas to flow from the gas supply device to the gas retaining layer as opposed to liquid pressure, but the liquid cannot flow through the gas permeable tarp towards the gas supply device, for example, if the liquid pressure is temporarily higher than the gas pressure in the gas supply device.
[0071] Preferably, the gas-permeable canvas comprises a woven or non-woven textile, a woolen material, a porous ceramic, a porous metal, a felt composed of polymeric or metallic fibers and / or a metallic fabric. The gas-permeable tarpaulin can, for example, be woven with polymeric fibers or made with a felt or non-woven fabric composed of polymeric fibers. A gas-permeable tarp made of a polymer can attach to the gas-retaining layer, especially by lamination. As an alternative, or in addition, the gas-permeable tarpaulin may comprise a fabric composed of metallic threads, in particular corrosion resistant metallic threads, for example, high-grade rust resistant steel threads, with which a high level of resistance mechanical wear, resistance to UV radiation and chemical influences is advantageously obtained. Alternatively, the gas-permeable tarpaulin may also comprise a wool material, for example, polymer wool or elastomer wool, composed in particular of a foamed material. Thus, the weight of the gas-permeable tarpaulin is advantageously reduced. In addition, a gas-permeable tarpaulin preferably comprises a sintered material, such as, for example, a porous sintered material composed of metallic particles. Preferably, the gas-permeable tarpaulin is connected to the gas retaining layer by means of an adhesive. Alternatively, the gas retaining layer and the gas permeable tarpaulin are connected to each other by welding, in particular by ultrasonic welding (ultrasonic welding). Preferably, the gas-retaining layer and the gas-permeable tarpaulin are formed in one piece with each other, for example, from a polymer by means of a (continuous) molding or casting process.
[0072] The gas-permeable tarpaulin is preferably in the form of a porous semipermeable membrane, in particular microporous or nanoporous. The gas-permeable tarpaulin is in particular in the form of a gas-permeable metallic foil made of a polymer. Gas-permeable metal sheets can, for example, have a thickness of about 0.5 μm to 5 μm. Thus, it is possible to provide a thin and light surface coverage. In particular, metal sheets made of polymer can connect to the gas-retaining layer by lamination.
[0073] Preferably, the gas-permeable tarpaulin is in the form of a hydrophobic or super-hydrophobic tarpaulin. In other words, the gas-permeable tarpaulin repels water and other polar solvents, whereby said polar solvents are advantageously prevented from entering the gas-permeable tarpaulin.
[0074] Preferably, the gas supply device is in the form of a gas-permeable layer disposed on the side facing the body of the gas-permeable layer. In particular, the gas supply device also comprises a porous material with continuous pores. The gas permeability through the gas supply device is suitably higher than the gas permeability through the gas permeable tarpaulin.
[0075] Preferably, the gas supply device is in the form of an aerenchyma. An aerenchyma is an air passage structure in aquatic plants that allows the transport and storage of gas. In particular, the term “aerenchyma” is understood as a form of basic plant structure in which the intercellular spaces are large enough to form a true “air passage structure.” It is found, especially in plants swamp and aquatic plants and serves for the gas exchange of the plant's submerged organs.
[0076] In other words, the gas supply device is in the form of a gas tank, so that, with increasing liquid pressure, the gas is displaced through the gas-permeable tarp back to the gas supply device. gas and stored there so that it is moved to the gas retention layer again through the gas permeable tarpaulin in case of reduction of the liquid pressure. The gas supply device may, for example, have a porous material where the gas is stored. In addition, the material can be resiliently expandable, so that the volume increases as the gas pressure increases and the gas is forced through the gas-permeable tarp to the gas retention layer thanks to the resilient force of the material. It is also preferable that the internal walls of the gas supply device, which make contact with the gas, are at least regionally hydrophobic in nature. It is advantageously possible for the gas in the gas retaining layer to be temporarily stored in the gas supply device, instead of being released from the gas retaining layer, in the event of fluctuations in the liquid pressure.
[0077] Preferably, the gas retention layer has recesses or depressions at least regionally on the side facing the liquid, where the surface of the gas retention layer is preferably hydrophobic in the region of the recesses or depressions . For example, the gas retaining layer can be made of hydrophobic material. Alternatively, the gas retaining layer may comprise a hydrophilic material provided with a hydrophobic coating regionally. In particular, the hydrophobic coating can be formed only on the walls of the recesses or depressions. Particularly preferably, the gas retention layer is composed at least regionally of porous material, in which the recesses or depressions are formed by pores connected to the surface.
[0078] Preferably, the gas retention layer has protrusions or protruding elements at least regionally on the side facing the liquid, where the surface of the gas retention layer is substantially hydrophobic in the region of the protrusions or protruding elements. The spacing between the protruding elements is sized appropriately so that no liquid droplets are deposited between the protruding elements. The different liquid droplets are advantageously supported by several protruding elements, so that the interface between liquid and gas located between the protruding elements is substantially in the form of a wrap of the protruding elements. In particular, the spacing between two adjacent protruding elements can be from about 50 μm to about 500 μm, preferably from about 100 μm to about 200 μm.
[0079] Preferably, the protrusions or protruding elements have a central hydrophilic surface region surrounded by a hydrophobic surface region thereof. The interface between liquid and gas is advantageously located in regions of a hydrophilic nature. In this way, the separation of gas bubbles by the liquid flow is more advantageously prevented.
[0080] Preferably, the gas retention layer is divided into several sub-regions (also called "compartments") by means of fluid impermeable partitions. Fluid should be interpreted as a gas, a liquid or a mixture of both. Therefore, the partition prevents the flow of liquid or the flow of gas between adjacent subregions. It advantageously happens that, in the presence of a pressure differential between two adjacent sub-regions, the partitions prevent the gas from flowing from one sub-region to another, the resistance to flow in relation to the liquid with which it is made contact increases locally and on the other hand, the excess gas is released into the liquid from the sub-region to which the gas flows.
[0081] Preferably, the partitions are built in one piece or integrally with the other elements of the gas retention layer. It is also preferable that several hydrophobic protruding elements are located in a two-dimensional arrangement in all subregions of the gas retention layer.
[0082] Preferably, the gas retention layer comprises an embossed plastic resin or an embossed lacquer. In particular, the gas retention layer can be molded from a liquid plastic resin, where, preferably, it is possible for protruding elements to be formed integrally or in one piece next to a base canvas of the retention layer of the gas and / or gas permeable tarpaulin. In particular, the base tarpaulin of the gas retaining layer may be identical to the gas permeable tarpaulin.
[0083] Preferably, the gas retention layer is coated at least regionally with polytetrafluoroethylene (PTFE), also known by the trade name Teflon, or derivatives thereof. In particular, the coating can also comprise microparticles or nanoparticles of polytetrafluoroethylene or other materials. The coating made of PTFE advantageously acts as a hydrophobic layer and as an anti-adhesion agent, in order to prevent the adhesion of liquids or solids to the gas retention layer. The coating of the gas retention layer is preferably from about 0.15 nm to about 500 nm in thickness. Surface coverage according to an aspect
[0084] One aspect refers to a surface cover for a body that can be placed in contact with a liquid, which comprises: - a retention layer at least part of the gas, which is designed and arranged to make contact, at least regionally through a side facing the liquid, with the liquid; - at least one gas discharge device, which has a gas discharge opening on the liquid side of the gas retention layer; - a gas supply device, which connects to the gas discharge device, in which the gas fed by the gas supply device leaves the gas discharge device and is received at least in part in the gas retention layer .
[0085] Preferably, the gas discharge device extends through the gas retaining layer. In other words, a gas discharge opening for the gas holding device is formed on the liquid side of the gas holding layer.
[0086] Preferably, the gas supply device is in the form of a gas-permeable layer disposed on the side facing the body of the gas-permeable layer. Particularly preferably, the gas supply device is in the form of an aerenchyma. For greater advantage, the gas supply device easily and fluidly connects to various gas discharge devices, where the gas discharge devices can, in particular, be arranged evenly or irregularly over an area.
[0087] Furthermore, preferred features of the gas retention layer and the recesses, depressions or protruding elements thereof, as described with reference to the aspect of the invention above, can be included analogously in this embodiment. Structure according to an aspect
[0088] One aspect concerns a structure comprising: - a surface cover according to the invention, and - a gas source fluidly connected to the gas supply device of the surface cover.
[0089] Preferably, the gas source comprises a compressor, a pressure vessel for storing gas, a gas generation reactor or other devices capable of supplying gas at a gas pressure sufficient to cause the gas to flow at gas retention layer. Preferably, the gas generation reactor is a combustion engine whose exhaust gases are used to maintain the gas layer.
[0090] Preferably, the arrangement also comprises: - at least one sensing device to determine the gas content in the gas retention layer of the surface cover, and - a regulating device, which receives measurement data from at least a sensing device and which regulates the flow of gas from the gas source to the gas supply device based on these received measurement data.
[0091] For greater advantage, it is possible, thanks to the regulating device, to maintain a constant gas pressure or a constant gas layer thickness within the gas retention layer. Preferred sensing devices therefore comprise pressure sensors, ultrasound sensors and / or sensors for determining the thickness of the gas layer. Alternatively, a regulating device configured to feed gas to the gas retention layer at predetermined time intervals can be included. Use according to aspect
[0092] One aspect refers to the use of a surface cover according to the invention, in which the surface cover covers at least regionally one face of a body, in which, if the body is submerged in at least one liquid regionally on the face covered by the surface cover, a gas layer permanently separates the liquid and the submerged region from each other at least regionally.
[0093] It is advantageously the case that the body is not wetted by the liquid at least regionally, thus protecting it against corrosive liquids. Furthermore, it is advantageously the case that the body moves in relation to the liquid using less force because the resistance to flow is reduced thanks to the liquid-gas interface.
[0094] The body can, in particular, be a vessel, in such a way that the fuel consumption is advantageously reduced thanks to the lower resistance to the flow between the vessel wall and the water. In addition, the gas layer between the ship's wall and the water advantageously protects against corrosion of the ship, especially in seawater, and against fouling with organisms, for example, algae, mussels, barnacles and others. In other words, the surface covering according to the present invention has an anti-fouling action advantageously possible to dispense with the use of biocides, poisonous substances that dissolve in water over time.
[0095] Preferably, the surface of the body is a wall of a vessel or a structure disposed in the water, or an internal wall of a vessel of liquid or a liquid duct. Use according to aspect
[0096] One aspect refers to the use of a surface cover according to the invention, in which the surface cover covers at least regionally a mounting face of a body, in which, if the body is submerged in a liquid through the mounting face covered by the surface cover, a gas layer permanently separates the liquid and the mounting face from each other, such that a second body is installed on the mounting face so that a gas layer is located at least regionally between the body and the second body.
[0097] Thanks to the gas layer, it is advantageously possible to install the second body on the first body substantially without contact and without friction.
[0098] Preferably, the face of the body is a hole whose inner wall forms the mounting surface. Preferably, the second body to be installed is therefore an axis, so that the system composed of the body with the surface cover and the axis acts as a ball bearing. Description of the figures
[0099] Hereafter, preferred embodiments of surface coverage will be explained by way of example and based on the attached drawings, among which:
[00100] figure 1: illustrates a sectional view through a preferred embodiment of a structure of a surface covering over a body,
[00101] figure 2: illustrates another embodiment of a structure of a preferred surface covering over a body,
[00102] figure 3: illustrates preferred embodiments of a gas retention layer of the surface covering,
[00103] figure 4: illustrates other preferred embodiments of the gas retention layer,
[00104] figure 5: illustrates another embodiment of a surface covering,
[00105] figure 6: illustrates another embodiment of a surface covering,
[00106] figure 7: illustrates another preferred embodiment of the gas retention layer of a surface cover in a first condition,
[00107] figure 8: illustrates the embodiment illustrated in figure 7 in a second condition,
[00108] figure 9: illustrates another embodiment of a gas retaining layer of a preferred surface cover in a first condition,
[00109] figure 10: illustrates the embodiment illustrated in figure 9 in a second condition,
[00110] figure 11: illustrates another embodiment of a gas retention layer,
[00111] figure 12: illustrates another embodiment of a gas retention layer in different conditions,
[00112] figure 13: illustrates two embodiments of a hydrophobic gas retention fiber,
[00113] figure 14: illustrates two other embodiments of a hydrophobic gas retention fiber,
[00114] figure 15: illustrates another embodiment of a hydrophobic gas retention fiber,
[00115] figure 16a: illustrates a perspective view of a preferred gas retention layer,
[00116] figure 16b: illustrates a perspective view of a preferred gas retention layer,
[00117] figure 16c: illustrates a perspective view of a preferred gas retention layer,
[00118] figure 16d: illustrates a perspective view of a preferred gas retention layer,
[00119] figure 17a: illustrates a plan view of the gas retention layer shown in figure 16,
[00120] figure 17b: illustrates a plan view of another preferred gas retention layer,
[00121] figure 17c: illustrates a plan view of another preferred gas retention layer,
[00122] figure 17d: illustrates a plan view of another preferred gas retention layer,
[00123] figure 18: illustrates a preferred gas retention layer,
[00124] figure 19: illustrates different surface structures,
[00125] figure 20: illustrates a structure of a gas retaining layer on the wall of a ship,
[00126] figure 21: illustrates a surface structure equipped with depressions,
[00127] figure 22: illustrates a surface structure equipped with depressions with hydrophobic coating,
[00128] figure 23: illustrates a ship whose wall is provided with several plates with a gas retention layer,
[00129] figure 24: illustrates a surface cover, or plate, that has partitions 42,
[00130] figure 25: illustrates a plate or board,
[00131] figure 26: illustrates a section through a ship wall with plates,
[00132] figure 27: illustrates a gas retention layer in the form of a single stage system and in the form of a double stage system,
[00133] figure 28: illustrates a formed gas retention layer
[00134] by an uneven surface, figure 29: illustrates a gas retention layer formed
[00135] by an uneven surface, figure 30: illustrates a gas retention layer formed
[00136] on a filiform element, figure 31: illustrates a gas retention layer formed
[00137] on a filiform element, figure 32: illustrates a gas retention layer formed
[00138] on a filiform element, figure 33: illustrates a gas retention layer formed
[00139] on a filiform element. Figure 1 illustrates a wall 2 of a body designed to be submerged at least regionally in a liquid 4. On the liquid side of wall 2, a surface cover 6 is arranged and / or attached to wall 2 at least regionally.
[00140] The surface cover 6 comprises a retention layer at least partial of gas 10 that makes contact, at least regionally through a side facing the liquid 10a, with the liquid 4. The surface cover 6 further comprises a gas permeable tarp 12 arranged and / or attached to a side facing the body 10b, located opposite the liquid facing side 10a, of the gas retention layer 10. In the preferred embodiment illustrated in figure 1, the retention layer gas 10 and the gas permeable tarpaulin 12 are formed in one piece or integrally. However, it is evident that the gas-retaining layer 10 and the gas-permeable tarpaulin 12 can be formed apart from one another and connected or linked together.
[00141] The surface cover further comprises a gas supply device 14 connected to the gas permeable tarpaulin 12. In other words, the gas supply device 14 and the gas permeable tarpaulin 12 connect at least fluidly to each other. another so that gas flows from the gas supply device 14 to the gas retaining layer 10 through the gas permeable tarp 12. In the embodiment shown in figure 1, the gas supply device 14 is in the form of a conductive duct of gas disposed between the gas permeable tarpaulin 12 and the wall 2. Preferably, the gas supply device 14 can also be in the form of a gas permeable layer, in particular porous, in which the porous space of the supply device The gas feed preferably has continuous pores for the gas to flow through the gas supply device along the longitudinal direction L. The gas supply device thus advantageously feeds gas to the gas permeable tarp 12 over an area, which gas then flows through the gas-permeable tarpaulin 12 to the gas retention layer 10, preferably along an outlet direction A, which can be oriented substantially perpendicular to the longitudinal direction L. Preferably, the gas supply device 14 also serves to connect the gas permeable tarpaulin 12 and the gas retaining layer 10 connected to it to the wall 2. The gas supply device 14 and the gas permeable tarpaulin 12 can, for example, mechanically connect to each other, for example, by adhesive bonding or laminating, so that the surface cover 6 connects to the body because one side facing the body of the gas supply device 14 connects to wall 2. Also preferably, it is possible that the gas permeable tarpaulin 12 and the gas supply device 14 are formed in one piece or integrally with each other. Particularly preferably, the gas retaining layer 10, the gas permeable tarpaulin 12 and the gas supply device 14 are formed together in one piece. The gas supply device 14 connects fluidly through a duct 16 to a gas source 18, in which the amount of gas flowing to the gas supply device 14 is regulated or controlled by a valve 20 and a flow device. regulation 22 connected to said valve. The preferred embodiment illustrated in figure 1 further comprises a sensing device 24 configured to determine the gas content in the gas retention layer 10 of the surface cover 6. This can be done, for example, by the reflection of an ultrasound signal or of an electromagnetic wave. Preferably, the sensing device 24 measures the gas content in the gas retaining layer 10 without making contact with it, so that the sensing device 24 does not need to be installed so that it is wetted by liquid 4. In particular, the sensing device 24 can be arranged on one side with its back to the liquid of the wall 2, the measurement of the gas content being preferably made through the wall 2. Based on the amount of gas within the gas retention layer 10 on the surface cover 6 as measured by the sensing device 24, the regulating device 22 determines the amount of gas that must be fed to the gas retaining layer 10 through the gas supply device 14 to keep the amount of gas constant in the gas retention layer 10 or the thickness of the gas layer in the gas retention layer 10, and therefore the spacing between the liquid-gas contact face and the wall 2.
[00142] The gas retention layer 10 comprises several protruding elements 26 made of hydrophobic material or coated with hydrophobic material. The protruding elements 26 are arranged on the gas retention layer 10 at regular or irregular intervals along the longitudinal direction L. The gas that emerges through the gas-permeable canvas 12 is retained by the protruding elements 26 in the volumes located between them, in so that the liquid 4 is substantially prevented from entering the volumes formed between the protruding elements 26. More specifically, the liquid 4 is prevented from wetting the gas permeable canvas 12. The protruding elements 26 illustrated in figure 1 have a tower structure, which is, in particular, advantageously easy to manufacture. However, it is evident that other models of the protruding elements 26 can also lead to the desired effect. Other advantageous models of protruding elements 26 are illustrated in figures 3 and 4.
[00143] Figure 2 shows a section through another embodiment of a structure of a surface cover 6 on the wall 2 of a body. The gas retention layer 10 comprises several protruding elements 26 in the form of thin capillaries with a diameter of about 1 μm to about 100 μm and made of hydrophobic material. The protruding elements 26 of the gas retention layer 10 are integrally connected to the base 10c of the gas retention layer 10. The side facing the body 10b of the gas retention layer 10 is arranged and / or connected to the wall 2 of the body. The connection of the gas retaining layer 10 with the wall 2 can be made, for example, by adhesive bonding using an adhesive. In addition, the gas retention layer 10, preferably, can also be formed by applying a substantially liquid material to the wall 2 and solidifying it into the shape of the gas retention layer 10.
[00144] The embodiment illustrated in figure 2 comprises a gas discharge device 28 that connects fluidly through a gas supply device 14, in the form of a duct, to an adjustable gas source 18. The amount of gas fed the retention layer 10 through the gas discharge device 28 is regulated or controlled by the valve 20, the regulating device 22 and, preferably, the sensing device 24. In this case, the control or regulation is carried out analogously to the described embodiment with reference to figure 1.
[00145] Through the gas discharge device 28, the gas is conducted to the intermediate spaces formed between the protruding elements 26. It is evident that the gas emerging from the gas discharge device 28 can flow along the longitudinal direction L through the intermediate spaces formed between the protruding elements 26. Since the embodiment illustrated in figure 2 has a gas source 18 disposed on one side facing the liquid of the wall 2, the gas supply device 14 crosses the wall 2 in at least a dot. It is evident that the gas supply device 14 can extend along the longitudinal direction L both on the liquid side of the wall 2 as well as on the liquid back side of the wall 2 in order to supply various discharge devices for gas 28. Therefore, wall 2 may have several through-holes, each assigned to a different gas discharge device 28. Therefore, it is advantageously possible to feed gas to the gas retention layer 10 over a given area.
[00146] Figures 3a to 3f illustrate different shapes of the protruding elements 26. The protruding elements can, for example, have a shape corresponding to the capillaries in the leaves of the aquatic macrophyte Salvinia molesta. These protruding elements 26 comprise a stem 26a, which projects substantially at right angles from the base 10c and from whose head 26b several branches 26c extend that separate from each other and join at the ends at a common end point 26d . Thanks to the appearance of this protruding element 26, it is also said to have the shape of an egg beater.
[00147] Figure 3b illustrates an alternative model of protruding crown-shaped elements, which have one, two or more pairs of rods 26a of concave-convex shape, which rods connect, through a first final region, to the base 10c and which extend, in an opposite end region, along a direction substantially perpendicular to the base 10c, in which the spacing between said end points is less than the spacing between the stems 26a in the middle of the stems.
[00148] Figure 3c illustrates several protruding elements 26 in the form of thin capillaries whose diameter can be from about 1 μm to about 100 μm, preferably from about 10 μm to about 50 μm.
[00149] Figure 3d illustrates protruding elements 26 in the form of towers whose shape, seen in section, is substantially rectangular. However, the towers can also be substantially cylindrical, oval, prismatic or in other similar shapes.
[00150] Figure 3e illustrates protruding elements 26 in the form, each, of a capillary with a spherical tip end 26f at the end of capillary 26 located opposite the base 10c.
[00151] Figure 3f illustrates protruding elements 26 substantially truncated with a spherical tip end 26f at the tip of the trunk. It is evident that, in the embodiments illustrated in figures 3e and 3f, it is also possible to use a spheroidal shaped tip end.
[00152] Figures 4a to 4f show modified protruding elements 26 substantially corresponding to the protruding elements shown in figures 3a to 3f. However, the protruding elements 26 in the embodiments illustrated in figures 4a to 4d have a hydrophilic surface region 26e. Preferably, the hydrophilic surface region 26e is arranged or formed in a central region of the surface of the protruding elements 26. The hydrophilic surface region 26e is, in particular, surrounded by a hydrophobic surface region of the protruding elements 26. The region of hydrophilic surface 26e is advantageously suitable to ensure that the contact surface between the gas retained in the gas retention layer 10 and the liquid 4 with which it is contacted is located in the hydrophilic surface region. In this way, it is also advantageously possible to prevent the rupture of the contact surface between the gas and the liquid in said locations, thus reducing the gas losses of the gas retention layer 10.
[00153] Figure 4e illustrates protruding elements 26 each in the form of a capillary with a spherical tip end 26f at the end of capillary 26 located opposite base 10c, where a hydrophilic region 26e is formed at the tip end spherical. It is evident that the spherical tip may also be hydrophilic in nature.
[00154] Figure 4f illustrates protruding elements 26 substantially tapered with a spherical tip end 26f at the tip of the trunk, in which a hydrophilic region 26e is formed at the spherical tip end. It is evident that the spherical tip may also be hydrophilic in nature. It is also evident that, in the embodiments illustrated in figures 4e and 4f, it is also possible to use a spheroidal shaped tip end.
[00155] Figure 5 shows a section through another embodiment of the surface cover 6 arranged on a wall 2. Like the embodiment illustrated in figure 2, the embodiment illustrated in figure 5 has a gas discharge device 28, which connects to a gas supply device 14 that passes through the wall 2. The gas retaining layer 10, which, by means of a side facing the body 10b, is arranged and / or connected to the wall 2, comprises depressions 30 instead of protruding elements. The depressions 30 comprise a through opening 32 on the liquid side of the gas retaining layer 10, wherein the diameter of the through opening 32 is preferably smaller than that of the depressions 30. In particular, the depressions 30 can be substantially spherical. However, it is clear that the depressions 30 can also be polygonal or oval.
[00156] The material of the gas retention layer 10 where the depressions 30 are formed is hydrophobic. However, it is evident that the inner wall of the depressions 30 in the gas containment layer 10 can also be coated with hydrophobic material.
[00157] The gas that emerges through the gas discharge opening 28 can be stored or retained in the depressions 30 of the gas retention layer 10. Thanks to the surface tension on the contact surface between the gas and the liquid 4 with which if contact is made, the contact surface between the gas and the liquid protrudes beyond the surface of the solid material of the gas retention layer 10, that is, beyond the area of the passage opening 32. Thus, a pocket is formed of gas between the liquid 4 and the wall 2, or the solid material of the gas retention layer 10, at least in the region of the depressions 30.
[00158] Figure 6 illustrates a modified form of the embodiment illustrated in figure 5, where like elements are indicated by like reference symbols. The depressions 30 formed in the gas retention layer 10 have a hydrophobic coating 34 on the inner wall of the depressions 30, so that the solid material of the gas retention layer does not need to be entirely composed of hydrophobic material. The contact surface between gas and liquid is formed analogously to the embodiment illustrated in figure 5.
[00159] To further minimize the flow resistance of a liquid flow along the longitudinal direction L on the contact surface between the liquid and the solid material of the gas retention layer 10, the gas retention layer 10 may have at least regionally a surface coating 36 with an adhesion reducing material. The surface coating can, for example, comprise microparticles or nanoparticles that form a defined surface roughness in the range of about 10 nm to about 10 μm. In addition, the surface coating can also be a continuous coating of Teflon or Nano Teflon, which can have a coating thickness of about 0.15 nm to about 500 nm. Furthermore, to form a surface structure, the surface coating 36 preferably comprises particles made of polymers, PDMS, silicon, silicon dioxide, silicon hydroxide, metals, in particular steel and steel fibers, and epoxy resins.
[00160] Figure 7 illustrates a structure composed of similar protruding elements 26 and 27, in which the protruding elements 26 and 27 are of different sizes. Therefore, the protruding elements 27 protrude from the base 10c towards the liquid 4 more than the protruding elements 26 by a factor of about 1.1 to about 2. This results advantageously in two structuring plans of the liquid interface -gas. Said structures advantageously have the effect of preventing the total elimination of the gas, which is retained in the gas retention layer 10, in regions thereof.
[00161] In the case of slow flow velocities of the liquid 4 along the longitudinal direction L or in the case of a small positive pressure of the liquid 4 in relation to the gas pressure within the gas retention layer 10, the liquid-gas boundary it runs substantially in the form of a wrapper of the tip regions 27d of the protruding elements 27 that project beyond the wall 2 than the protruding elements 26. This advantageously gives rise to a substantially continuous air layer sustained or supported substantially only by the protruding elements 27. Advantageously, the friction between the liquid 4 and the wall 2 decreases considerably, for example, to less than 5% of the friction value if there was no gas in the gas retention layer 10. However, in this condition , the gas retention layer 10 shows a slight tendency to gas loss in the event of pressure fluctuations between the gas 5 trapped in the gas retention layer and the adjacent liquid 4. In other words, the force per unit area, or activation energy per unit area, required for the escape of gas bubbles or for the separation of gas bubbles is relatively low.
[00162] Figure 8 illustrates the embodiment illustrated in figure 7 after a loss of gas from the gas retention layer 10. The liquid-gas boundary now traces substantially a wrapper of protruding elements 26 that project less towards the liquid 4. The different gas-filled regions of the gas retention layer 10 formed by the intermediate spaces between the protruding elements 26 are bounded by the protruding elements 27, which now project regionally into the liquid 4. In particular, the gas exchange between different regions formed by the protruding elements 27 are avoided by them.
[00163] The reduction in resistance to flow remains significant in this condition, but it decreases considerably in relation to the condition illustrated in figure 7. However, the base 10c remains spatially separated substantially entirely, that is, in about 90% at about 98% of liquid 4 by gas 5 in the gas retention layer 10. The force required for the flow of liquid 4 to remove more gas 5 from the gas retention layer 10 is advantageously greater in the condition shown in figure 8 than in condition illustrated in figure 7. Therefore, it is advantageously the case that, after an initial gas loss from the gas retention layer 10, relatively larger amounts of gas are prevented from being released from the gas retention layer .
[00164] In the case of even more gas losses from the gas retention layer 10, for example, due to very high pressure fluctuations between the gas and the adjacent liquid 4, a small volume of gas remains in the hydrophobic niches between the protruding elements 26. Thus, although the effect of reducing the friction of the gas layer with respect to the resistance to the flow of a liquid 4 flowing along the longitudinal direction L decreases, it is advantageously the case that only up to about 10% of the surface of the base 10c will make direct contact with the liquid 4, so that there is still a substantially complete separation between the wall 2 or the base 10c and the liquid 4.
[00165] Figures 9 and 10 illustrate a modified embodiment of the surface cover 6 shown in figures 7 and 8. Like elements are therefore indicated by like reference symbols. The protruding elements 26 and 27 additionally comprise hydrophilic surface regions 26e and 27e, which allow for improved adhesion of the interface between liquid and gas to the protruding elements 26 and 27, in particular to the tip regions 26d and 27d of them. This local fixation of the gas-liquid boundary is also called “pinning”, so that the hydrophilic surface regions 26e and 27e can also be called “pinning centers”. It is advantageously the case that, with the inclusion of the hydrophilic surface regions 26e and 27e, the force per unit area needed to detach the gas bubbles from the gas retention layer 10 increases, thereby decreasing gas losses from the gas retention 10. Advantageously, this also results in less resistance to flow in the gas retention layer 10 and in better separation between liquid 4 and base 10c or wall 2.
[00166] Preferably, it is also possible to form other hydrophilic surface regions (not shown) on the base 10c between the protruding elements 26e and 27e. These hydrophilic surface regions prevent the separation or exit of the gas that has accumulated in the region adjacent to base 10c. This gas that accumulates in the base 10c serves advantageously as a final reservoir of gas that can only be eliminated with difficulty and that, in particular, covers about 60% to about 98% of the surface of the base 10c or of the wall 2 and, therefore, , separates the covered surface from the liquid 4. Advantageously, it also happens that the surface of the wall 2 is protected substantially entirely from oxidation or corrosion by a small volume of gas. Advantageously, it also happens that the remaining gas residues in the base 10c act as nuclei for restoring the gas layer by means of the gas supply device (as illustrated, for example, in figures 1, 2, 5 and 6).
[00167] Furthermore, of course, it is also possible to form three or more hierarchical structures of protruding elements in the gas retention layer 10. In other words, in addition to the protruding elements 26 and 27 illustrated in figures 7 to 10, it is possible to include other protruding elements, which protrude from the base 10 towards the liquid 4 more than the protruding elements 27.
[00168] It is evident that the protruding elements 26 and 27 can be spatially distributed in a regular, almost regular or random manner in the gas retention layer 10. In addition, depressions or recesses that serve as gas pockets, that is, as reservoirs gas, can be included in several locations. Porous surfaces, whose pores on the surface serve as depressions or gas pockets, are also suitable for surface coatings with a certain roughness. For example, the depressions 30 of figures 5 and 6 can also be formed in that the base c is made of a porous material, the pores of which, in the region of the passage openings 32, connect to the outside of the base 10c.
[00169] In the event that the protruding elements 26 and 27 are structured to project towards the liquid 4 by several different lengths, it is particularly preferable that the relatively long protruding elements, which determine the position of the liquid-gas interface in figures 7 and 9, also have a relatively low area density (number of protruding elements 27 per square centimeter). In contrast, the protruding elements 26 that determine the liquid-gas interface in the situation where the gas retaining layer has already lost a non-negligible amount of gas, as shown in Figures 8 and 10, preferably have a relatively high area density . It is also preferred that said protruding elements 26 are relatively small in diameter and have hydrophilic surface regions, if any, of relatively small size or diameter.
[00170] Preferably, it is possible that protruding elements 26 and 27, which are made of a super-hydrophobic material or have a hydrophobic or super-hydrophobic surface, are provided with hydrophilic surface regions when forming the surface of the protruding elements 26 and 27 by application or growth of nanoparticulate material and then, or at the same time, making the nano-rugged surface thus formed hydrophobic with apolar hydrophobic end groups or tetrafluoroethylene groups or by the absorption of molecules based on tetrafluoroethylene or other non-polar molecules or hydrophobic or organic or inorganic fats or oils. Said hydrophobic regions can then become less hydrophobic in a directed manner by interaction with plasma. Those regions whose hydrophobia is reduced, in other words, which have a hydrophilic function conferred to them, can, for example, be tips, capillary ends, elevations, protruding corners and higher edges, rugged surfaces and the like.
[00171] If the surfaces of protruding elements 26 and 27 are conductive of electricity, for example, if electrically conducting polymers are used to form protruding elements 26 and 27, then an electrical discharge can be used to decrease hydrophobia, electrical discharge the one that, thanks to the tip effect, preferably happens exactly at the most intense tips and curvatures and at the most protruding points of the surfaces, that is, precisely where the hydrophilic surface regions are preferably arranged. Upon discharge, the hydrophobic protective layer is locally destroyed at the loading points, thus forming relatively hydrophilic surface regions in relation to the hydrophobic regions of the protruding elements 26 and 27.
[00172] Figure 11 illustrates a structure composed of protruding elements 26 of substantially uniform size, in which the gas retention layer 10 has an uneven surface 38, which is preferably formed with uniform roughness both in the region of the base 10c and in the region of the protruding elements 26. Therefore, the structures of the bumpy surface, preferably, can be smaller in size than that of the protruding elements 26 by a factor of about 5 to about 20. The bumpy surface can also have a distribution multimodal roughness that encompasses roughnesses of about 10 μm to about 3 mm, in which, in particular, the protruding elements 26 can be considered the greatest roughness within the roughness distribution.
[00173] This advantageously gives rise to two or more plans for structuring the liquid-gas interface, as already described in relation to figures 7 to 10. The statements made on the basis of these apply analogously to the embodiment illustrated in figure 11. Advantageously , the bumpy surface 38 has the effect of preventing the total elimination of gas, which is trapped in the gas retention layer 10, in regions thereof.
[00174] Preferably, it is also possible that the protruding elements 26 have hydrophilic surface regions 26e that allow better adhesion of the interface between liquid and gas to the associated protruding elements 26. It is evident that the bumpy surface 38 may have a regular, almost regular or random spatial surface structure.
[00175] Figures 12a to 12c illustrate an embodiment similar to that illustrated in figure 11. In the condition illustrated in figure 12a, the gas retention layer 10 is completely filled with gas 5. After a loss of gas from the layer for gas retention 10, the liquid-gas interface moves as shown in figure 12b. As a result of a new loss of gas, the liquid-gas interface moves as shown in figure 12b. As a result of the gas loss, although the resistance to the flow of wall 2 in relation to a liquid 4 in flux increases, the liquid is substantially prevented from coming into direct contact with the gas retention layer 10 or with the wall 2, protecting thus the wall 2, for example, against the corrosive influence of the liquid.
[00176] Figures 13a and 13b illustrate fibers 40 whose hydrophobic surfaces are provided with protruding elements 26 and 27. In this case, figure 13a illustrates a structure or arrangement of protruding elements 26 as also shown in figure 1. Figure 13b illustrates a structure or arrangement of protruding elements 26 and 27 as also shown in figures 9 and 10. The fibers 40, therefore, have the properties described with respect to said figures. As an option, the protruding elements can be provided with hydrophilic regions 26e and 27e. The fibers 40 can act as protruding elements of the gas retention layer of the surface cover and be formed integrally with it.
[00177] Figures 14a and 14b illustrate fibers 40 with an annular structure of protruding elements 26 and 27 corresponding to the structures illustrated in figures 13a and 13b. As an option, it is also possible to form hydrophilic regions 26e and 27e in rings 26 and 27 that extend along the circumference of the fibers 40.
[00178] Figure 15 illustrates a fiber 40 whose hydrophobic bumpy surface 38 has a structure or arrangement as shown in figure 11.
[00179] Each of the figures 16a to 16d illustrates a perspective view of a two-dimensional arrangement of the protruding hydrophobic elements 26 of a gas retention layer 10. Figure 17a illustrates a plan view of the preferred two-dimensional arrangement illustrated in figure 16a.
[00180] The protruding elements 26 are designed in the format illustrated in figure 3a. However, it is evident that the protruding elements can also be of any other suitable model, for example, the models illustrated in figures 3 and 4.
[00181] As shown in figures 16a and 17, the two-dimensional arrangement of protruding elements 26 is divided into individual subregions 44, called "compartments", in which each subregion 44 of the gas retention layer 10 comprises several elements protruding 26. Preferably, individual subregions 44 are bounded in relation to adjacent subregions 44 or in relation to their surroundings by a fluid impermeable partition 42. Fluid should be interpreted as a gas, a liquid or a mixture of Consequently, partition 42 prevents the flow of a liquid or gas between subregions 44. More specifically, in the presence of a pressure differential between two adjacent subregions 44, dividers 42 advantageously prevent gas to flow from a subregion 44 to the adjacent subregion, and thus, resistance to flow with respect to a liquid with which contact is made increases locally.
[00182] In particular, it prevents the situation in which a subregion 44 is charged with gas beyond its capacity by the influx of gas, with the gas then passing into the liquid and thus being lost.
[00183] Preferably, partitions 42 are made of the same material as protruding elements 26. In particular, the gas holding layer 10 can be formed by protruding elements 26 and partitions 42 together or in one piece. It is also preferable that the partitions 42 of a subregion 44 have substantially the same height as the protruding elements 26 contained in the subregion 44. It is also preferable that the protruding elements 26 have hydrophilic surface regions 26e and / or that the partitions 42 have hydrophilic surface regions 42a.
[00184] As shown in figure 16b, it is also possible that the protruding elements 26 are of a totally hydrophobic nature, whereas the fluid impervious partitions 42 have hydrophilic surface regions 42a.
[00185] As an alternative, the partitions 42 can also be made entirely or regionally of hydrophilic material, as shown in figure 16a, whereas the protruding elements 26 can be totally hydrophobic or they can (not shown in figure 16c) have hydrophilic surface regions 26a, analogously to the protruding elements 26 illustrated in figure 16a. For example, it is possible that only the surfaces of the partitions 42 facing the liquid are hydrophilic in nature or provided with a hydrophilic coating.
[00186] Finally, partitions 42 can also form a sub-region 44 by itself, as shown in figure 16d. In other words, subregion 44 does not comprise any protruding elements. Preferably, base 44a of subregion 44 has a hydrophobic surface. The partitions can be totally or regionally hydrophilic in nature. For example, it is possible that only the surfaces of the partitions 42 facing the liquid are hydrophilic in nature or provided with a hydrophilic coating. In particular, partitions 42 may be of a substantially hydrophobic nature, with a hydrophilic area or linear region formed on the upper edge, that is, on the surfaces of partitions 42 facing the liquid, preferably being the case that said region hydrophilic is continuous or is not interrupted by one or more hydrophobic regions, so that the gas exchange between two adjacent subregions 44 is effectively prevented even along the upper edges of the partitions 42. In this case, the partitions may contain a volume self-sufficient from subregion 44, so that the gas is retained within said subregion 44 and substantially cannot escape an adjacent subregion.
[00187] It is evident that the various embodiments of the protruding elements 26 can be combined in any desired way with the various embodiments of the partitions 42 in order to form a (self-sufficient) subregion 44.
[00188] In particular, at least one subregion 44, optionally with a partition 42 or several divisions 42, can be constructed as a board or board that can be attached to the body. In particular, a board or board (hereinafter also called air boards) can have a multiplicity of more than 1,000, more than 10,000 or more than 100,000 sub-regions 44. It is advantageously possible for a wall of any size to be fitted or clad several of these plates or planks with a gas retaining layer, which would also advantageously result in a flexible unit and would have the effect that only a small number of different plates or planks would need to be provided.
[00189] Sub-regions 44 are molded or formed, and connected to the body, so that the longitudinal extent of sub-regions 44 is smaller in the vertical direction than in the horizontal direction perpendicular to it. In particular, if subregions 44 are connected to a ship's hull, the longitudinal extent is advantageously less along the direction of the gravitational force (vertical) than along the direction of the water flow while the ship is moving (substantially horizontal) because with the gas contained in the gas retention layer, thanks to the then smaller spacing of the partitions 42, the pressure differential between two adjacent subregions 44 decreases. At the same time, greater spacing between partitions 42 along the horizontal allows to minimize the hydrophilic regions where friction occurs between the water and the ship.
[00190] Sub-regions 44, therefore, are preferably rectangular, as shown in figure 17a.
[00191] However, it is clear that subregions 44, preferably, can also be hexagonal or honeycomb, triangular, quadrangular or in other shapes. Figure 17b illustrates a plan view of a preferred embodiment in which partitions 42 are arranged to form quadrangular subregions 44. Figure 17c illustrates a plan view of a preferred embodiment in which partitions 42, which are of the same length , are arranged to form hexagonal subregions 44. Figure 17d illustrates a plan view of a preferred embodiment in which partitions 42 are arranged to form elongated alveolar or hexagonal subregions 44. Coating for the protection of surfaces submerged in liquid
[00192] In short, one aspect describes a method for obtaining anti-fouling action and protection against corrosion or chemical attack for surfaces submerged in liquid by using a coating that retains a layer of gas submerged in liquid.
[00193] The surface (for example, of the ship, tube, window, measuring instrument, water vessel, etc.) can be additionally provided with a coating that provides chemical or biological anti-fouling action through a layer containing substances toxic or biocidal or other additives. The advantage is that the active substances are only released when necessary, more specifically when the surface is briefly discovered by a gas layer and comes into contact with water or marine organisms. Thus, the release of toxic additives or biocides occurs only rarely, more specifically precisely when necessary; with the result that the amount of toxic substances released in the liquid, for example, in sea water or fresh water, per unit of time and area decreases by many orders of magnitude, which, in turn, has two advantageous effects: (i) the release of toxic and biocidal substances decreases dramatically, with no reduction in the anti-fouling action, and (ii) as a result, the length of time for which the reserve of these substances in the ship's paint layer or coating lasts before being consumed until the anti-fouling action decreases is also drastically prolonged, thus also extending maintenance intervals for ships and other facilities. This is a huge advantage, especially in the case of oil platforms, marine wind farms and other objects that are difficult to access.
[00194] The anti-fouling action can be obtained by using air retention layers, or, more generally, gas retention layers, submerged in water alone or together with the addition, through the gas layer, of gases or toxic or biocidal aerosols or having an effect on biological scale in some other way.
[00195] The gas layer alone already constitutes a barrier that prevents marine organisms from establishing themselves. This applies, in particular, to the establishment of bacteria, diatoms, single-celled organisms and micro-organisms that constitute the so-called sludge or that are responsible for micro-encrustation and that generally form the basis for the establishment of larger organisms. If the surface, for example, of a ship, etc., is surrounded by a layer of air and does not come into contact with water, the establishment and reproduction of these organisms is no longer possible.
[00196] The surface (for example, of the ship, tube, window, measuring instrument, water vessel, etc.) can additionally be provided with a coating that provides chemical or biological anti-fouling action through a layer containing substances toxic or biocidal or other additives. The advantage is that the active substances are only released when necessary, more specifically when the surface is briefly discovered by a gas layer and comes into contact with water or marine organisms. Thus, the release of toxic additives or biocides occurs only rarely, more specifically precisely when necessary; with the result that the amount of toxic substances released in the liquid, for example, in sea water or fresh water, per unit of time and area decreases by many orders of magnitude, which, in turn, has two advantageous effects: (i) the release of toxic and biocidal substances decreases dramatically, with no reduction in the anti-fouling action, and (ii) as a result, the length of time for which the reserve of these substances in the ship's paint layer or coating lasts before being consumed until the anti-fouling action decreases is also drastically prolonged, thus also extending maintenance intervals for ships and other facilities. This is a huge advantage, especially in the case of oil platforms, marine wind farms and other objects that are difficult to access.
[00197] The encrustation of ships and other vessels and of technical installations, walls, structures etc. exposed to water due to the growth of biological systems is a major technical problem in both fresh and salt water. In the case of the encrustation of ships, this is aggravated by the fact that the encrustation considerably increases the friction of the ships with the water and, therefore, also the fuel consumption. The previous solution to protect against this type of encrustation, to equip ships etc. with paints, varnishes and toxic coatings, it is no longer acceptable for environmental protection reasons and is increasingly prohibited because it has been proven that these highly poisonous coatings from ships release considerable amounts of poisonous substances and compounds, especially heavy metals and compounds heavy metals in sea water.
[00198] Non-toxic substances that offer adequate protection against bio-encrustation, however, have yet to be discovered. The chances of this happening, even in the future, are low because, on the one hand, the systems must prevent the biological encrustation of marine organisms, but, on the other hand, these systems must not, specifically by their action, harm marine organisms to do not harm the fauna and flora of the seas and slopes. The problem, seen in this way, potentially constitutes an inherent contradiction. It is therefore necessary to find a way to selectively compromise aquatic and marine organisms on the surface without causing significant damage to organisms in the surrounding fresh or salt water ecosystem. The present invention provides a technical solution to that approach.
[00199] As, on the one hand, marine organisms and other living organisms that seek to settle on the ship or on other technical surfaces in fresh water and salt water must be prevented from settling and combated, but the measures must act quite selectively only in these surfaces and do not damage biological organisms or marine organisms in other places, it is evident the use of a local measure related exclusively to the surfaces that must be protected and their immediate surroundings.
[00200] With the method and device according to the invention, the specified technical problem is solved as follows: as it is technically possible to retain layers of gas on a surface submerged in water and introduce gas into the said layer in a manner directed through layers of porous fabric or of small openings or nozzles, it is evident to equip the surface that must be protected with a gas retention surface or layer of that type and, at regular, irregular intervals or when necessary, that is, when it starts or in the presence of biological fouling, introduce a gas or aerosol (with correspondingly active solid particles) that combats said fouling in the gas layer across the surface. The treatment has no specific side effects for the ecosystem if the gas or aerosol is only slightly soluble in water, if the compound dissolves after some time in non-poisonous constituents or is only toxic at high concentrations or if it is used only with CO2 to smother marine organisms that settle on the surface of the ship. In this case, treatment and dosing can be done manually or automatically.
[00201] Variants and optional features refer to • combination with sensing means and / or cameras for automatic detection of the content and / or type of biological encrustation, with or without quantitative assessment of the degree of encrustation. • combination with sensing means and / or spatially selective cameras for the automatic detection and localization of biological encrustation, with or without quantitative degree assessment. • possibility of spatially selective discharge of the gas or aerosol selectively active in the locations where the fouling occurred or is beginning. • possibility of spatially selective dosing depending on the intensity and type of encrustation. • gas sensing means for spatially resolved detection of the gas composition or concentration of the active substance in the gas layer. • gas analysis by gas extraction or aerosol from the layer, also together with mass spectroscopy, IR analysis, gel chromatography, gas chromatography etc. for spatially and / or temporally resolved analysis of the concentration of the composition and / or active substance in the gas layer. • concomitant analysis of components dissolved from the gas or aerosol in the surrounding water in order to keep them below specified limit values always and in all locations, to safely comply with all environmental requirements in all locations and always and to interrupt manually or, preferably, automatically the treatment whenever necessary by the immediate interruption of the gas or active aerosol supply.
[00202] The anti-fouling action can also be achieved by using air-retained layers submerged in water together with toxic materials, additives and surface coatings.
[00203] The encrustation of ships and other vessels and of technical installations, walls, structures etc. exposed to water due to the growth of biological systems is a major technical problem in both fresh and salt water. In the case of the encrustation of ships, this is aggravated by the fact that the encrustation considerably increases the friction of the ships with the water and, therefore, also the fuel consumption. The previous solution to protect against this type of encrustation, to equip ships etc. with paints, varnishes and toxic coatings, it is no longer acceptable for environmental protection reasons and is increasingly prohibited because it has been proven that these highly poisonous coatings from ships release considerable amounts of poisonous substances and compounds, especially heavy metals and compounds heavy metals in sea water.
[00204] Non-toxic substances that offer adequate protection against bio-encrustation, however, have yet to be discovered. The chances of this happening, even in the future, are low because, on the one hand, the systems must prevent the biological encrustation of marine organisms, but, on the other hand, these systems must not, specifically by their action, harm marine organisms to do not harm the fauna and flora of the seas and slopes. The problem, seen in this way, potentially constitutes an inherent contradiction. It is therefore necessary to find a way to selectively compromise aquatic and marine organisms on the surface without causing significant damage to organisms in the surrounding fresh or salt water ecosystem. The present invention provides a technical solution to that approach.
[00205] As, on the one hand, marine organisms and other living organisms that seek to settle on the ship or on other technical surfaces in fresh water and salt water must be prevented from settling and combated, but the measures must act quite selectively only in these surfaces and do not damage biological organisms or marine organisms in other places, it is evident the use of a local measure related exclusively to the surfaces that must be protected and their immediate surroundings.
[00206] Highly efficient ship linings to prevent fouling with aquatic or marine organisms already exist. The problem with these coatings is that they are toxic; they must or at least should be so to be effective in preventing the establishment of marine organisms. The problem with these coatings is that, as a result of long-term and long-lasting contact with water, the poisonous compounds and heavy metals go into salt water.
[00207] The method according to the invention and the coating according to the invention deal with the following: coatings that are efficient in preventing fouling are maintained, and the anti-fouling action is thus guaranteed and technically proven. The use may be not only of newly developed antifouling coatings, but also of coatings proven over the years and decades. Their release into the surrounding water and, therefore, into the surrounding ecosystem, however, is prevented because the surface with the anti-fouling coating is in the form of an air-trapping or gas-trapping surface, and the water, therefore, does not it does not come into contact with the surface with the anti-fouling coating because a permanent layer of air or gas, which in particular persists even under operational conditions, is located between the (possibly toxic) surface and the water. In the case of gas losses as a result of peak loads, the layer is, in a preferred variant of the method, recharged with gas ("regenerated"): it is technically possible, according to an invention deposited in parallel, that a layer of gas of said gas is kept on a surface submerged in water and the gas is introduced into said layer in a directed manner through layers of porous tissue or small openings or nozzles. Thus, it is possible, in the case of gas loss, that the layer is immediately regenerated again. Capillaries, fibers, pillars, ridges or pins etc., which “transpose” or maintain the air layer, can but do not necessarily have to confer anti-fouling action themselves or through their coating.
[00208] Variants and optional features refer to • combination with an automatic sensing medium, preferably spatially selective, to monitor air losses. • combination with a sensing means of the said type with an automatic refueling device, preferably spatially selective, to ensure the constant presence of the gas layer and avoid lasting contact between sea water and the anti-fouling coating. • concomitant analysis of toxic components dissolved in the surrounding water from the liner to keep them below specified limit values at all times and in all locations and to safely comply with all environmental requirements in all locations and at all times. • use of the method and the device even in fresh water. • use of the method and the device even with lacquers, coatings, paints and others containing toxic substances, antibiotics, biocides or heavy metals. • use of method and device even with non-poisonous lacquers, coatings and paints. • use of the gas layer also to reduce the friction of the ship, boat, etc. • use of the techniques, methods and devices mentioned according to the invention in fresh water or in brackish water or in sea water. • use of the techniques, methods and devices mentioned according to the invention not only for the surface of ships, but also for the external and internal surfaces of other technical components that make contact with water, for walls, structures etc. submerged in corresponding water and for pipes, bathtubs etc.
[00209] The anti-fouling action through the use of air retention layers submerged in water can be obtained solely thanks to the action of the gas layer or in combination with ultrasound, deformations and mechanical movements, shock waves, repeated heat treatment of the surface (for example, by electrical heating of capillaries, tissues, etc. that conduct electricity) or UV treatment or electrical pulses including gases generated when electrochemical decomposition of water or salt water or sea water.
[00210] The encrustation of ships and other vessels and technical installations, walls, structures etc. exposed to water due to the growth of biological systems is a major technical problem in both fresh and salt water. In the case of the encrustation of ships, this is aggravated by the fact that the encrustation considerably increases the friction of the ships with the water and, therefore, also the fuel consumption. The previous solution to protect against this type of encrustation, to equip ships etc. with paints, varnishes and toxic coatings, it is no longer acceptable for environmental protection reasons and is increasingly prohibited because it has been proven that these highly poisonous coatings from ships release considerable amounts of poisonous substances and compounds, especially heavy metals and compounds heavy metals in sea water.
[00211] Non-toxic substances that offer adequate protection against bio-encrustation, however, have yet to be discovered. The chances of this happening, even in the future, are low because, on the one hand, the systems must prevent the biological encrustation of marine organisms, but, on the other hand, these systems must not, specifically by their action, harm marine organisms to do not harm the fauna and flora of the seas and slopes. The problem, seen in this way, potentially constitutes an inherent contradiction. It is therefore necessary to find a way to selectively compromise aquatic and marine organisms on the surface without causing significant damage to organisms in the surrounding fresh or salt water ecosystem. The present invention provides a technical solution to that approach.
[00212] The use of air-trapped or gas-trapped surfaces submerged in water forms the basis for the method proposed in this document and device according to the invention. As it is technically possible, according to the invention deposited in parallel, that layers of gas are retained on a surface submerged in water and that gas is introduced into said layer in a directed manner through layers of porous tissue or small openings or nozzles, it is evident to equip the surface to be protected with a surface or layer of gas retention of this type and to initially eliminate the contact between biological systems and the surface that must be protected simply by means of the gas layer itself. This mechanical contact is, however, necessary as a starting point for adhesion and is, however, prevented by a layer of air or gas.
[00213] If this contact and, ultimately, the encrustation, however, occur, for example, as a result of impacts, intense friction etc., other measures to physically combat marine organisms can be additionally implemented at regular intervals, irregular or when necessary, that is, at the beginning or in the presence of biological encrustation, in order to avoid the use of chemicals harmful to the environment, in which two methods are particularly suitable: (i) reduction and mechanical elimination of the adhesive contact between marine organisms and the surface to which they attach by the movement of elastic capillaries, by shock waves or by ultrasound, and (ii) local heating (in particular resistive, by induction, by microwave or by a combination of these methods ) for the thermal destruction of the adherent cell layer.
[00214] In a preferred variant of the method, the structures (capillaries, fibers etc.) with the effect of retaining the air on the surface are conductive in nature and are heated directly. As an alternative, or in addition, it is possible that the surface, especially the aerenchyma claimed in an invention deposited in parallel to this patent, is of an electrically conductive nature and serves local heating.
[00215] In another variant of the method, it is also possible that radiation, for example, ultraviolet light, is used together with the air-holding surface.
[00216] Variants and optional features refer to • use of metallic surface structures. • use of the method and the device even in fresh water. • use of the method and the device even with lacquers, coatings, paints and others containing toxic substances, antibiotics, biocides or heavy metals. • use of the method and the device even together with non-poisonous lacquers, coatings and paints. • use of the gas layer also to reduce the friction of the ship, boat, etc. • coating of ship surfaces, in whole or in part. • use of the techniques, methods and devices mentioned according to the invention in fresh water or in brackish water or in sea water. • use of the techniques, methods and devices mentioned according to the invention not only for the surface of ships, but also for the external and internal surfaces of other technical components that make contact with water, for walls, structures etc. submerged in corresponding water and for pipes, bathtubs etc.
[00217] In other words, (preferred) topics of the application can be described according to the following:
[00218] The inventive material 1 refers to a coating for the protection of a surface or interface, which is permanently or intermittently exposed in whole or in part to a liquid, against corrosion, chemical attack and / or ) encrustation, characterized by the fact that the surface or interface is coated so as to retain a permanent or intermittently existing continuous or discontinuous gas layer submerged in liquid and by the fact that said gas layer protects the surface against said corrosion, said chemical attack and / or said (bio) encrustation.
[00219] Inventive material 2 refers to a coating, according to inventive material 1, characterized by the fact that protection against fouling refers to bio-fouling, especially in the form of micro-fouling, macro-fouling, to attack by algae, mussels and / or other marine organisms or a combination of these forms.
[00220] Inventive material 3 refers to a coating, according to inventive material 1 or 2, characterized by the fact that the used coating, which is covered permanently or intermittently in whole or in part by the gas layer itself , comprises biocides, TBT, copper, silver, heavy metals, metal compounds, metal complexes, metal alloys or other fouling reducing components or mixtures and the fact that the gas layer decreases the release rate of these substances ( quantity of these substances released per unit of time and area).
[00221] Inventive material 4 refers to a coating, according to inventive material 1, characterized by the fact that the coating for the protection of surfaces is applied to the surface of ships, yachts, boats and other vessels or installations and technical structures installed at sea, in particular oil platforms, marine wind turbines, steel structures, concrete structures or other technical installations installed in a fixed position or not fixed position in the sea or in fresh water, buoys, ducts and cables, drive devices, ship surfaces, ship propellers and control devices, windows, etc. that are intermittently or permanently submerged in water or are bathed in water, ship rudders, reflectors and other light-emitting optical functional units.
[00222] Inventive material 5 refers to a coating, according to inventive material 1, characterized by the fact that the gas in the continuous or discontinuous gas layer, permanently or intermittently, is air, nitrogen, oxygen, carbon dioxide , argon, helium or mixtures of these gases, and / or the liquid is water, salt water, sea water or alcohol or aqueous or alcoholic solutions.
[00223] Inventive material 6 refers to a coating, according to inventive material 1, characterized by the fact that the coating comprises structures, pillars, capillaries, rods.
[00224] Inventive material 7 refers to a coating, according to inventive material 1 or 6, characterized by the fact that the structures, pillars, capillaries, rods or other structures of the coating surface have a height of 0, 02 mm to 2 mm and have a hydrophobic surface with or without adhesives, end surfaces or hydrophilic side surfaces.
[00225] Inventive material 8 refers to a coating, according to inventive material 1, characterized by the fact that the gas retention coating is applied to the outside or inside of pipes or reaction vessels for chemical reactions or inside vessels for storing liquids.
[00226] Inventive material 9 refers to a coating, according to inventive material 1, characterized by the fact that air is retained using the Salvinia effect, the Notonecta effect or through hierarchically structured surfaces.
[00227] The inventive material 10 refers to a coating, according to inventive material 1, characterized by the fact that the discontinuous gas layer is composed of a regular, partially regular or irregular distribution of gas bubbles in the coating of surface.
[00228] Figure 18 illustrates a preferred model of gas retention layer with several hydrophobic protuberances which, as an option, have a hydrophilic tip end which, during operational use, faces the water. The gas retention layer is arranged on a lacquer, which optionally comprises a biocide or copper. Device for obtaining a layer of gas submerged in liquid
[00229] In short, one aspect describes layers of gas on surfaces submerged in liquid, which are of great technological interest for reducing friction in the case of ships and pipes and for protecting the surface from fogging, the (bio) fouling, corrosion and chemical attack.
[00230] By structuring suitable surfaces, it is possible for a layer of gas or gas bubbles, which adheres to the surface, to be submerged in liquid. The problem is that a gas layer of that type only remains stable for a limited time and then is lost. This problem is solved by means of a layer that can be refilled with gas.
[00231] According to one aspect, the present invention combines (1) a structured layer that retains a layer of gas or gas bubbles submerged in liquid, with (2) a refill system composed, for example, of (i) gas supply lines or ducts and nozzles or microbocals or (ii) a membrane, textile, woven system, felt system, wool system, porous fiber or sintered layer system or (iii) gas recharge due to bubbles of (microscopic) gas generated, for example, by a sneezer being captured by surface capillaries or surface structures that preferably have liquid-repellent surfaces, and with (3) a refill device composed of, for example, ( i) a gas pump or (ii) a self-refilling means, for example, that uses the negative pressure generated by an object that moves in relation to the liquid, or by a flow, or (iii) a sneeze to the external generation of air bubbles that are then captured by the structured surface.
[00232] As the gas lost from the gas layer can be refilled again, the gas layer is maintained, and performs its desired function in the long run. In a variant, the demand for recharging is measured by means of sensors, and the recharge of the layer with gas takes place automatically.
[00233] Air layers on surfaces submerged in water are of great technological interest, for example, and, in particular, for reducing friction in the case of ships and in piping and piping systems in order to prevent deposits and formation unwanted mucous membranes on surfaces submerged in liquid, and to obtain anti-fouling action and protection against corrosion and the chemical attack of surfaces submerged in liquid, in each case by using a coating that retains a layer of gas or a layer of bubbles of gas or gas bags submerged in liquid.
[00234] By structuring suitable surfaces, it is possible, using textiles, structured and / or functionalized coatings, for example, with coatings biologically inspired by the example of water spiders or Salvinia molesta or Notonecta glauca, to dip a layer of gas, for example, from air, if the surface is submerged in liquid from the gaseous atmosphere, for example, in water from the air. The problem is only that this layer of air, typically 1 μm to 1 mm thick, adheres to the surface only for a limited time, with the aforementioned gas layer, then, getting lost, usually in the form of the emission of gas bubbles from the gas layer.
[00235] The present invention now solves said problem thanks to the device according to the invention combining at least two of the following three items: (1) a structured layer that holds gas submerged in liquid or a structured layer that holds gas bubbles or gas bags submerged in liquid (see figures 19 to 21), with (2) a refill duct system composed, for example, of (i) supply lines or ducts for the gas supply and nozzles or microbocals or (ii) a membrane, textile system, fabric system, felt system, wool system, porous fiber or sintered layer system or (iii) recharge the surface by means of a capture device for gas bubbles or gas bubbles microscopically generated, for example, by a sneezer, said capture device being composed, for example, of capillaries or surface structures with liquid-repellent surfaces with or without hydrophilic centers and which, in the form of capillaries, pilare protruding crowns or crowns or the formation of corresponding hollows or depressions with a liquid-repellent coating, capture gas bubbles from the liquid and pin them to the surface or integrate them with an existing gas layer, and with (3) a refill, for example, in the form of (1) a pump or other active refill device or (ii) a self-refill means, for example, that uses the negative pressure generated by a vessel that moves in relation to the liquid or by the negative pressure generated by a flow of liquid in relation to a float, measuring station, wall etc. stationary (the pressure differential is generated by velocity flow v = 0.5 • liquid density • v2) or (iii) a sneezer for the external generation of gas bubbles that are then captured by the structured surface (see point (2)).
[00236] As an alternative, it is also possible for a liquid or solid substance to be dosed which, on its own or by chemical reaction with the surrounding liquid, releases a gas and, thus, develops or complements the gas layer or bubble layer of gas again (“refueling”).
[00237] As the gas lost from the gas layer can be refilled again, the gas layer is kept on the surface submerged in liquid and performs its desired function, even in the long term.
[00238] The gas layer can also be replaced by a layer composed of different gas bubbles or gas bags (air bags) or by a layer that comprises them.
[00239] In a variant of the method, the demand for refill is measured by sensors and, to replace the missing gas or the gas that the gas layer has lost, as a whole or selectively in the region to which the respective sensor is associated, feeds gas to the corresponding region once again by triggering the gas pump or the sneezer or by opening the corresponding gas valves (“gas refill on demand”). In this variation of the method, the demand for recharge is, therefore, measured by sensors, and the lost gas or the gas missing from the layer is automatically recharged by means of the device according to the invention.
[00240] The initial development of a gas layer can of course also be carried out in this way, if desired.
[00241] A device for retaining a layer of air submerged in water, or, more generally, a layer of gas submerged in liquid, is characterized by the fact that the layer can, in the case of gas loss, be recharged through a gas-permeable sub-canvas, which can be a textile sub-canvas, some other fabric or felt, a wool material, a porous ceramic layer or ceramic layer suitable for the diffusion of gas, a metallic layer with pores, a felt metallic or metallic screen, a semipermeable membrane, a porous, microporous or nanoporous layer - preferably hydrophobic or super-hydrophobic (preferably constructed on the basis of polymers, ceramic materials, metals or composites).
[00242] The retention of a layer of gas submerged in liquid, for example, submerged in water, is of great technical interest. There is great potential for use for surfaces of this type, for example, in the field of ship coverings, among others, to reduce friction and obtain anti-fouling effects.
[00243] These surfaces are already produced in scale in the laboratory. Among others, the Salvinia effect, the hierarchical structuring based on the example of Notonecta, and the effects of shark skin and dolphin skin were successfully implemented.
[00244] The problem is that, in adverse operational conditions (wave surge, wave impact in the case of ship coverings etc.) or for relatively long periods of time, the loss of local or extensive gas, partial or total, occurs in certain places or as a whole.
[00245] In the method and device according to the invention, area elements (which are the subject of the present invention) are used together with a device, said elements being such that, after a partial or total loss of gas, they they can receive gas again. The device according to the present invention for retaining a layer of air submerged in water or, more generally, a layer of gas submerged in liquid, is characterized by the fact that the layer can be refilled via a gas-permeable sublone. , which can be a textile sub-canvas, some other fabric or felt, a wool material, a porous ceramic layer or ceramic layer suitable for the diffusion of gas, a metallic layer with pores, a metallic felt or metallic fabric, a semipermeable membrane, a porous, microporous or nanoporous layer - preferably hydrophobic or super-hydrophobic (preferably constructed on the basis of polymers, ceramic materials, metals or composites).
[00246] In a variant of the method, an aerenchyma, as described in an invention deposited in parallel, is used to recharge the gas.
[00247] Variants and optional features refer to • combining the loading above the gas layer ("replenishment") with other devices to artificially refill or replenish the gas layer, for example, capillaries, membranes, textiles etc. • coating surfaces with Teflon, polytetrafluoroethylene and their derivatives, in particular also microparticles and nanoparticles of these substances. • coating the surfaces with commercially available anti-adhesion sprays or else microparticles and nanoparticles. • use of surface structures made of polymers, resins, PDMS, silicon, silicon dioxide and silicon hydroxide, metals, steel and steel fibers, high grade steel, epoxy. • Embossing of lacquer surface structures, including ship lacquer, with and without functionalization or subsequent surface coating, for example, with Teflon or Nano Teflon (preferred layer thickness from 0.15 nm to 500 nm). spositive as described immediately above possibly also coupled with measurement and / or control and / or regulation devices that measure and control the condition of the gas layer as a whole or in a spatially resolved manner and automatically trigger the gas refill, if necessary. • coating of ship surfaces, in whole or in part. • use of metallic surface structures. • use of surfaces with a continuous air layer. • use of surfaces that form, develop or retain a regular or irregular pattern of gas bags or gas bubbles submerged in liquid. • use of hydrophobic or super-hydrophobic surfaces and surface structures for gas holding surfaces. • use of capillaries, pillars, crown structures, egg beater structures, towers and other raised structures, which are preferably provided with a liquid-repellent coating (with a hydrophobic or super-hydrophobic coating if the liquid water) for surfaces in order to retain gas in or between these structures. • use of depressions, hollows, holes, recesses and other lowered structures, which are preferably provided with a liquid-repellent coating (with a hydrophobic or super-hydrophobic coating if the liquid is water) for the surfaces in order to retain gas in or between said structures. • use of a combination of capillaries, pillars, crown structures, egg beater structures, towers and other raised structures, and depressions, hollows, holes and recesses, which are preferably provided with a repellent coating to liquid (with a hydrophobic or super-hydrophobic coating if the liquid is water) for surfaces in order to retain gas in or between said structures. • use of valves and internal flow regulators and actuating elements to control and / or regulate the gas supply to the outlet openings that perform the initial filling and replenishment of the gas layer. • use as a coating on ships, flow ducts, tubes and chemical reaction vessels.
[00248] In other words, the application's preferred topics can be described according to the following:
[00249] The inventive material 1 refers to a device and surface coating to load and retain a layer of gas submerged in liquid, composed of (i) a structured surface, structured surface coating or textile coating with a structure that allows , when submerged in liquid, permanently or at least for a brief period of time retain a continuous or discontinuous layer (this, that is, the discontinuous gas layer, being composed, for example, of gas bubbles or gas bags organized in regular or irregular way, gas bags or air bags, that is, small bags that are filled with liquid, formed in the topography of the surface), in which the surface structure can be a regular or irregular topographic structure (“relief” ), a spatially variant chemical functionality (chemical standard) or a combination of both, and (ii) a device that allows, in the event of gas loss, the surface to be recharged with gas, in which the gas is fed (a) from an external source, for example, in the form of small bubbles of gas that pass through the liquid, which are then captured by the structured layer, or (b) the gas is fed from an internal source from the layer, for example, from nozzles, pores, ducts or from a line system inside or below the structured layer, where the gas is fed, for example, from a gas reservoir, a pressurized gas reservoir, pressurized gas bottles or with the aid of a pump, or (c) the gas is generated directly in the layer, for example, by catalytic and / or electrochemical decomposition of the water or (d) the gas is extracted directly from the liquid in the form of dissolved gas present in the liquid or in the form of a liquid that evaporates into the gas layer and forms or replaces the gas or part of the gas in the continuous or batch gas layer or gas bubbles or air pockets in the liquid (“self-refilling gas layers”), in which the initial charge or recharge is carried out, for example, by means of a negative pressure effected by the relative movement between the liquid and the gas layer, for example, by a ship that moves in relation to the water.
[00250] The inventive material 2 refers to the use of the device and coating, according to the inventive material 1, characterized by the fact that said surface or interface, which is permanently or intermittently exposed totally or partially to liquid, is protected , by means of a gas layer submerged in a continuous or discontinuous liquid, permanently or intermittently, (i) against fogging, for example, by the interaction between organic and inorganic compounds and the biological and biogenic components of the liquid, and / or (ii) ) against corrosion and / or (iii) against chemical attack by liquid and / or gases, molecules, complexes, droplets (in the case of emulsions) or solid particles dissolved in the liquid and / or (iv) against (bio) fouling, where fouling may refer, in particular, to bio-fouling, in particular, in the form of micro-fouling, macro-fouling, algae attack, mussels, barnacles and / or other marine organisms or a combination of these.
[00251] Inventive material 3 refers to a coating, according to inventive material 1, characterized by the fact that the device and the coating for surface protection are applied to the surface of ships, yachts, boats and other vessels or to installations and technical structures installed at sea, in particular oil platforms, marine wind turbines, steel structures, concrete structures or other technical installations installed in a fixed position or not fixed position in the sea or in fresh water, buoys, conduits and cables, drive devices, ship surfaces, ship propellers and control devices, windows, etc. that are intermittently or permanently submerged in water or are bathed in water, ship rudders, reflectors and other light-emitting optical functional units.
[00252] Inventive material 4 refers to a device and coating, according to inventive material 1, characterized by the fact that the gas in the permanent or intermittently existing continuous or discontinuous gas layer is air, nitrogen, oxygen, dioxide carbon, argon, helium or mixtures of these gases, and / or the liquid is water, salt water, sea water or alcohol or aqueous or alcoholic solutions.
[00253] The inventive material 5 refers to a device and coating, according to inventive material 1, in which the surface coating comprises surface structures, pillars, capillaries, rods, which preferably have entirely or in part, a hydrophobic or super-hydrophobic surface, preferably characterized by the fact that said surface structures, pillars, capillaries, rods etc. they are, in turn, coated with a thin hydrophobic coating which is preferably 0.1 nm to 2 μm thick, in particular 0.1 nm to 100 nm thick.
[00254] Inventive material 6 refers to a coating, according to inventive material 1 or 5, characterized by the fact that the structures, pillars, capillaries, rods or other structures of the coating surface have a height of 0, 01 mm to 5 mm and have a hydrophobic surface with or without adhesives, end surfaces or hydrophilic side surfaces.
[00255] Inventive material 7 refers to a coating, according to inventive material 1, characterized by the fact that the gas retention coating is applied to the outside or inside of pipes or reaction vessels for chemical reactions or inside vessels for storing liquids.
[00256] Inventive material 8 refers to a coating, according to inventive material 1, characterized by the fact that air is retained using the effect of Salvinia, the effect of Notonecta or through hierarchically structured surfaces.
[00257] Inventive material 9 refers to a device and coating, according to inventive material 1, characterized by the fact that the surface coating involves textiles, fabrics, fiber composites or gas-permeable coatings, semipermeable membranes or microporous or nanoporous layers, and the fact that gas feeding and / or recharging is carried out through said pores and ducts in textiles, fabrics, fiber composites or gas-permeable coatings, semipermeable membranes or microporous or nanoporous layers.
[00258] Inventive material 10 refers to a device and coating, according to inventive material 1, characterized by the fact that the (re) charge of the surface with a gas layer or the gas recharge is carried out through small nozzles or microbocals embedded in the surface structure of the structured surface, which lie particularly preferably in the depressions of the surface layer, for example, at the base of capillaries, pillars or other elevated surface structures, where, in a preferred variant, structures or pillars themselves act as gas supply nozzles or microbocals.
[00259] Figure 19a illustrates a surface structure composed of elements in the form of an egg beater. Figure 19b illustrates a surface structure composed of crown-shaped elements. Figure 19c illustrates a surface structure composed of hydrophobic capillaries. Figure 19d illustrates a surface structure composed of tower-like elements.
[00260] Figure 20 illustrates an arrangement of a surface cover or a gas retention layer on the wall of a ship, in which the gas retention layer is fed with gas from the side facing the water.
[00261] Figure 21 illustrates a surface structure composed of depressions. Figure 22 also illustrates a surface structure composed of depressions, in which the surface optionally has a hydrophobic coating. Functional elements for applying a layer of gas submerged in liquid
[00262] In short, one aspect describes layers of gas on surfaces submerged in liquid, which are of great technological interest for reducing friction in the case of ships and pipes and for protecting the surface from fogging, the (bio) fouling, corrosion and chemical attack.
[00263] By structuring suitable surfaces, it is possible for a layer of gas or gas bubbles, which adheres to the surface, to be submerged in liquid. The problem is that these surfaces are generally complex in structure and generally difficult to produce over a large area, as would be necessary, for example, in the case of a ship's liner. Production directly at a shipyard or on the marine platform etc. it is also possible only with difficulty.
[00264] Said problems are solved by applying the structured gas retention surface to a modular support or by structuring the surface of the support itself, in which said modular support can be a rigid, elastic or ductile element in the form of “ plate ”or“ board ”or sheet metal or sheet metal element, which can preferably be made of polymer, ceramics, metal (steel, copper, silver etc.), textile, a porous material, a semiconductor material or others materials, and that has a structured surface or hierarchically structured surface to retain the air layer. The modular support itself is then applied, bonded, screwed, cemented, welded or machined, or reversibly or irreversibly connected by heat treatment, to the underlying surface, or otherwise fixed to the surface of the product or object that will be equipped with a layer of gas submerged in liquid.
[00265] One aspect refers to the modular connection of elements with friction reducing properties or anti-fouling properties or with properties to retain gas submerged in liquid or to generate or develop a gas layer.
[00266] The retention of a layer of gas submerged in liquid, for example, submerged in water, is of great technical interest. There is great potential for use for surfaces of this type, for example, in the field of ship coverings, among others, to reduce friction and obtain anti-fouling effects.
[00267] These surfaces are already produced in scale in the laboratory. Among others, the Salvinia effect, the hierarchical structuring based on the example of Notonecta, and the effects of shark skin and dolphin skin were successfully implemented.
[00268] The problem lies in the reversible and also retroactive and economical application of partially complex surface structures.
[00269] In the method and device according to the invention, modular area elements (which are the object of the present invention) with the aforementioned surface properties are used and which can be applied to the surface, for example, outside ships or inside pipes, even if retroactively, for example, by adhesive bonding.
[00270] Variants and optional features refer to • application in the form of boards, boards etc. with the desired surface properties; • application of flexible area elements; • application by reversible or irreversible adhesive bonding; • coating of ship surfaces, in whole or in part; • use of metallic surface structures; • use of surfaces and / or surface structures made of copper or silver; • use of surfaces and / or surface structures made of iron or steel; • use of surfaces, surface structures, pillars, ridges, fabrics, fiber structures, fiber felts and meshes made of iron or iron alloys, steel or high grade steel without or with a coating, in this case the said coating being realized preferably by thin polymeric coatings; • use of ceramic surface structures; • use of surfaces and / or surface structures made of polymers, resins, epoxy; • use of surfaces with a continuous air layer; • use of surfaces that form, develop or retain only a regular or irregular pattern of gas bags or gas bubbles submerged in liquid; • use of the aforementioned pattern of gas bags or gas bubbles submerged in liquid as a form of "ball bearing made of gas or air" - for mechanical orientation and / or reduction of friction; • use as a liner on ships, in ducts flow, in tubes and chemical reaction vessels; • combination of loading above the gas layer (“replenishment”) with other devices to artificially refill or replenish the gas layer, for example, capillaries, membranes, textiles, etc .; • coating the surfaces with Teflon, polytetrafluoroethylene and their derivatives, in particular also microparticles and nanoparticles of said substances; • coating the surfaces with anti-adhesion sprays available for sale or else microparticles and nanoparticles; • use of surface structures made of polymers, resins, PDMS, silicon, silicon dioxide and silicon hydroxide, metals, steel and steel fibers, high grade steel, epoxy; • embossing of lacquer surface structures, including ship lacquer, with and without subsequent functionalization or surface coating, for example, with Teflon or Nano Teflon (preferred layer thickness from 0.15 nm to 500 nm) ; • device as described immediately above, possibly also coupled with measurement and / or control and / or regulation devices that measure and control the condition of the gas layer as a whole or in a spatially resolved manner and automatically trigger the gas refill, if necessary; • coating of ship surfaces, in whole or in part; • use of metallic surface structures; • use of surfaces with a continuous air layer; • use of surfaces that form, develop or retain a regular or irregular pattern of gas bags or gas bubbles submerged in liquid; • use of hydrophobic or super-hydrophobic surfaces and surface structures for gas holding surfaces; • use of capillaries, pillars, crown structures, egg beater structures, towers and other raised structures, which are preferably provided with a liquid-repellent coating (with a hydrophobic or super-hydrophobic coating if the liquid water) for surfaces in order to retain gas in or between said structures; • use of depressions, hollows, holes, recesses and other lowered structures, which are preferably provided with a liquid-repellent coating (with a hydrophobic or super-hydrophobic coating if the liquid is water) for the surfaces in order to retain gas in or between said structures; • use of a combination of capillaries, pillars, crown structures, egg beater structures, towers and other raised structures, and depressions, hollows, holes and recesses, which are preferably provided with a repellent coating to liquid (with a hydrophobic or super-hydrophobic coating if the liquid is water) for surfaces in order to retain gas in or between said structures; • use of valves and internal flow regulators and actuating elements for the control and / or regulation of the gas supply to the outlet openings that perform the initial filling and replenishment of the gas layer; • use as a coating on ships, flow ducts, tubes and chemical reaction vessels.
[00271] A device for retaining a layer of air submerged in water, or, more generally, a layer of gas submerged in liquid, can be characterized by the fact that the gas layer is divided into individual "compartments"; area elements that, at the edge, are specifically protected against gas leakage in the edge region by relatively dense capillary zones, by hydrophilic networks or pins in a high density arrangement or by protruding hydrophilic walls, that is, hydrophilic walls that protrude upwards to a certain degree.
[00272] The retention of a layer of gas submerged in liquid, for example, submerged in water, is of great technical interest. There is great potential for use for surfaces of this type, for example, in the field of ship coverings, among others, to reduce friction and obtain anti-fouling effects.
[00273] These surfaces are already produced in scale in the laboratory. Among others, the Salvinia effect, the hierarchical structuring based on the example of Notonecta, and the effects of shark skin and dolphin skin were successfully implemented.
[00274] The problem, however, is that (i) the air escapes at the edges of the coating, and (ii) in the case of large surfaces covered with layers of gas, there are generally considerable pressure differentials between different points in the layer. An example is a vertical wall submerged in water. Thanks to hydrostatic pressure, which increases linearly with the depth of the water, different points on the surface are subjected to different static pressures. If the surface is equipped with a gas retaining layer and is therefore covered by a layer of gas submerged in liquid, the gas will be forced from regions of high pressure to regions of low pressure. A homogeneous thickness gas layer, therefore, is not formed and - even more seriously - the gas layer in the relatively high pressure zones will ultimately escape. (iii) a corresponding problem also occurs if the pressure gradient in the layer is not based on hydrostatic pressure, but on the dynamic pressure differentials, for example, thanks to different flow rates of the surrounding liquid at different locations on the surface.
[00275] In the method and device according to the invention, the problem is solved because the gas retaining surfaces do not retain a continuous gas layer, but, instead, the gas layer is divided into individual "compartments"; these segments are sealed against the gas flow and each one is small enough - in particular, in the presence of gravitational pressure gradients, it is small enough - that the pressure differences within a given compartment are small enough to avoid a considerably inhomogeneous distribution of the gas within a compartment, that is, to avoid considerable differences in the thickness of the air layer.
[00276] In another method according to the invention and another device according to the invention, it also happens that the edges of the gas holding surface and the edges of the different compartments are protected, by special measures, against the escape of gas in the edges, in which the said measures can be an increase in the area density of the gas retention structures, widening of the hydrophilic pins or the use of linearly extensive structures in a special hydrophilic coating of the boundary networks, capillaries or pins.
[00277] Variants and optional features refer to - application in the form of boards, boards etc. (hereinafter also called “air plates”) with the desired surface properties; - application of flexible area elements; - application by reversible or irreversible adhesive bonding; - coating of ship surfaces, in whole or in part; - use of metallic surface structures; - use of surfaces with a continuous air layer; - use of surfaces that form, develop or retain only a regular or irregular pattern of gas bags or gas bubbles submerged in liquid; - use of said pattern of gas bags or gas bubbles submerged in liquid as a form of ball bearing made of gas or air - for mechanical orientation and / or friction reduction; - use as a coating on ships, flow ducts, tubes and chemical reaction vessels.
[00278] The new concept of air plates: - metal plates and sheets or elements of metal sheets that retain a layer of gas submerged in liquid; - can be applied in a modular and flexible way to smooth or bumpy, curved or non-curved surfaces of any size; - can be easily applied to existing surfaces; - plates with an air layer - or more generally: a gas layer - submerged in liquid; - modular; - can be easily applied to existing surfaces; - plates, that is, area elements of any desired shape, which retain or develop a layer of gas submerged in liquid, for example, submerged in water; - and provisions of those elements; - and devices, for example, ships or pipes, which contain these elements on their external or internal surfaces; - plates, that is, area elements of any desired shape, which retain or develop a layer of gas submerged in liquid, for example, submerged in water; - and provisions of those elements; - including area elements that, in a periodic arrangement, fully cover the areas; - and devices, for example, ships or pipes, which contain these elements on their external or internal surfaces; - no high pressure gradient within a plate; - hydrostatic pressure differential within a plate equal to, at most, density of the liquid x height of the plate x gravitational acceleration; - problems resulting from edge effects are solved by compartmentalizing and sealing edges within a plate; - in the case of systems with a rechargeable gas layer, supply lines or gas charging systems can be integrated into the module or modular support; - modular concept; - simple installation; - simple replacement of damaged plates; - thanks to the flexible support, they can also be applied to curved surfaces; - reversible coating; - adhesive connection and disconnection already technically obtained; - do not require any specific ship construction; - do not require any specific underlying surface; - highly suited to the huge catering market; - and for new ships.
[00279] The new concept of air plates: - even partial coatings are possible; - short installation times; - suitable for a wide variety of ship sizes; - adaptation to larger scales is therefore very easily possible; - it is not necessary to produce large surfaces, only unit quantities of plates, sheet metal elements, large individual sheet metal rolls; - a wide variety of materials is possible for the air retaining layer, the support material and the adhesive; - this allows simple adaptation to ambient conditions (fresh water, salt water, etc.); - individual elements, preferably from 0.2 cm x 0.2 cm to 10 cm x 10 cm, within the surface of a support element (“air plate” or “plate”) are subdivided, as a surface unit air retention, by means of a terminal edge - preferably hydrophilic; - concept: create compartments for subdivision in order to prevent the exchange of air between the compartments; - 10 cm x 10 cm up to 100 cm x 100 cm as the preferred size for the air plates (with the formation of compartments inside each plate) and with installation of the air plates to cover larger areas; - reduction of friction with modular, spatially selective coating, where and according to what is necessary; - air retention under real operating conditions; - thanks to the modular approach, the simultaneous installation of different types of plates, metal sheets or sheet metal elements with different coatings at different points on the object to be coated, for example, the ship, is possible according to the locally required function, with locally prevailing pressure, flow conditions (for air retention) and light conditions (relevant due to bio-encrustation).
[00280] Modular concept: - simple installation; - simple replacement of damaged plates; - another advantage: detachment of the production site from the surface coating in relation to the place where said surface coating is applied to the surface, for example, to the ship. This is important because the production of surfaces, which are partly of a complex structure, to retain gas submerged in liquid requires a special production process that cannot be readily implemented in production facilities adjacent to each vessel that will be coated or even at sea. in the offshore sector. - another advantage: compact production plants because there is no need to produce extremely large surfaces, only plates, sheet metal elements or small sheet metal networks. - Another advantage: the size of the surfaces to be covered is not limited by the size of the production plant: with an adequate number of small slabs, it is possible to cover surfaces of any size. - consequent advantage: there is no need for the production process to be adapted to surfaces larger than the individual plate, the individual sheet metal sheet or the individual sheet metal element (= a surface element of a certain size and shape). - non-toxic; - economic; - Light; - visually attractive and can be adapted to the ship's appearance (color, livery, etc.); - non-combustible and non-flammable; - can be easily combined with plates based on other friction reduction technologies (plates with shark skin / dolphin skin, hydrophobic or super-hydrophobic surfaces, etc.); - no specific expertise required during the connection process; - no special equipment needed; - economical mass production of a standard product at the factory instead of inconvenient special coating using special machines on the ship.
[00281] Objective: air layers submerged in persistent water
[00282] Content: air retention on artificial surfaces
[00283] Air retention: - permanently or temporarily limited - negative pressure - in the flow gradient.
[00284] Advantages and properties - modular production, adaptable to any object sizes and object formats, surfaces can be covered entirely; - permanent air retention; - air retention at negative pressure; - air retention in the flow gradient.
[00285] Figure 23 illustrates a ship 2 'whose wall is provided with several plates 6 or boards ("air plates") so that, thus, a gas retention layer protects the ship's wall against the influence of water. .
[00286] Figure 24 illustrates a surface cover or plate 6 with dividers 42 for fluidly separating several regions of the gas retention layer 10 from one another.
[00287] Figure 25 illustrates a plate or board (“air plate”).
[00288] Figure 26 illustrates a section through a ship wall with plates 6 or boards ("air plates").
[00289] Use of air retaining or gas retaining surfaces
[00290] In short, one aspect describes the use of air retention or gas retention surfaces submerged in water or some other liquid in order to protect surfaces against corrosion by the liquid or by components, ions or additives and constituents contained in the liquid - including possible reactive solid particles contained in the liquid.
[00291] The protection of surfaces against corrosion is of great technical importance. In particular, solid body surfaces, for example, metal surfaces submerged in liquid, for example, in water, in particular sea water, are subjected to intense corrosive attack. The use of lacquer coatings that prevent corrosion is suitable in this case, although it is also associated with considerable disadvantages. These include, in particular: (i) over time, lacquers become brittle, cracked and detach, (ii) they generally release toxic constituents into water, (iii) they generally demonstrate long-term temperature resistance only limited in applications in the relatively high temperature range and (iv) they themselves are generally not - especially in the case of use in chemically aggressive media such as acids, brines, oxidants or strong reducers - adequately resistant to the liquid medium.
[00292] With the method and device according to the invention, the said four problems are solved because the liquid medium is totally prevented from making contact with the vessel or with the tube or other wall, and, instead, are used containers and vessels composed of air (or some other gas), that is, between the actual wall of the vessel or the actual wall of the tube or some other partition, a layer composed of a gas (preferably inert in the chemical environment in question), in the in the form of a gas layer, it is applied to the surface, thus preventing contact between the reactive liquid and the vessel wall, in which, for the application of a layer of persistent gas to the surface, a gas retention coating, for example, using the Salvinia effect or the Notonecta effect.
[00293] Variants and optional features refer to the use of the gas layer also for gas exchange, for the introduction of reaction gases (reagents), for the removal of reaction products or for cleaning and discharge purposes. • application of flexible gas retaining surface elements. • coating of ship surfaces, in whole or in part. • use of surfaces with a continuous air layer. • use of surfaces that form, develop or retain only a regular or irregular pattern of gas bags or gas bubbles submerged in liquid. • use of the said gas layer or of the said pattern of gas bags or gas bubbles submerged in liquid also to reduce friction. • use as a coating on ships, flow ducts, tubes and chemical reaction vessels.
[00294] The production of surfaces that retain liquid submerged gas using a periodic or non-periodic matrix of metallic pins (small bars or rods or metallic wires that extend perpendicularly or obliquely to the surface to which they are applied) preferably made high grade steel, with or without capillaries for refilling the gas layer, with or without the use of the Salvinia effect using a hydrophilic region at the end of a metal pin otherwise hydrophobic.
[00295] The retention of a layer of gas submerged in liquid, for example, submerged in water, is of great technical interest. There is great potential for use for surfaces of this type, for example, in the field of ship coverings, among others, to reduce friction and obtain anti-fouling effects.
[00296] The problem is to technically implement these surfaces, based on the example of Salvinia molesta or Notonecta glauca, for example, so that they demonstrate long service lives in the mechanically and chemically demanding operating conditions of offshore fleets, for example: • it is therefore necessary to guarantee the mechanical stability of the coating in the presence of intense undulation or wave surges • and the corresponding corrosion resistance under the corrosive action of sea water.
[00297] An ideal material that fulfills the two mentioned conditions is high grade steel. Therefore, in the method and device according to the invention, corresponding layers that retain air submerged in water are developed so that the main components of the layer, preferably also capillaries, pillars or other structures applied to the surface in order to retain the layer of air, be made of steel, preferably high grade steel resistant to rust.
[00298] Another advantage is that, in a variant of the method, the air retaining structures can be formed entirely or in part by high-grade steel cannulas, on the side or at the end where an opening is located through which layer of air or gas can be refilled ("refilled") with gas in the event of gas loss.
[00299] Other Variants or characteristics refer to the • application of metal sheets or steel sheets. • application of small metallic pin arrays. • use of steel, iron, iron alloys, other metals or carbon fibers as air retention structures. • use of metallic felts, metallic wire mesh or fabrics. • use of metal surface structures by embossing or other machining of metal surfaces. • use of embossed or otherwise structured metal sheets or plates, including the use of thin or extremely thin steel sheets. • use of surface structures that form, constitute or retain only a regular or irregular pattern of gas pockets or gas bubbles submerged in liquid, rather than a continuous gas layer. • use to reduce friction in liquid. • use as a coating on ships, flow ducts, tubes and chemical reaction vessels.
[00300] Use of air retention or gas retention surfaces submerged in water, or in some other liquid, to protect against adhesion to the solid wall or the vessel surface in the case of liquid solidification, for example, in the case of freezing water.
[00301] Vases in which a medium will be introduced for solidification, for example, water, for example in a freezer or in the ice compartment of a refrigerator, usually have two problems: (i) thermal contraction or expansion during the solidification process and (ii) the adhesion of the solidified medium to the vessel wall.
[00302] In the method and device according to the invention, the problem of adhesion is solved thanks to the vessel being equipped with a gas retention coating and the liquid itself does not come into contact with the vessel or tube walls. If the gas retaining structures are made to be elastic - preferably to be inclined to the surface - and also long enough that, during the phase change, they compensate for expansion or contraction by deformation of the structures and by change in its angle of inclination, and simultaneous change in the gas volume of the layer, the problem (i) is also solved. Alternatively, elastic vessel walls made of, for example, rubber, silicon rubber, etc. can be used, which then support the gas retention liner.
[00303] Other Variants or characteristics refer to • application in the form of boards, boards etc. with the desired surface properties. • application of flexible area elements. • application by reversible or irreversible adhesive bonding. • wall covering and vessel surfaces - in whole or in part. • use of metallic surface structures. • use of surfaces with a continuous air layer. • use of surfaces that form, develop or retain only a regular or irregular pattern of gas bags or gas bubbles submerged in liquid. • use of the aforementioned pattern of gas bags or gas bubbles submerged in liquid as a form of "ball bearing made of gas or air" - for mechanical orientation and / or reduction of friction. • use as a coating on tubes or vases chemical reaction.
[00304] Device to retain a layer of air submerged in water or, more generally, a layer of gas submerged in liquid, characterized by the fact that the gas layer is not continuous, but in the form of a matrix of small bubbles of gas at predefined points on the surface, in a preferred embodiment configured so that gas bubbles form at predefined points on the surface which, by topographic structure and / or by the chemical functionalization of the surface, demonstrate preference, in terms of energy, for the stabilization of gas bubbles, in which, in a preferred variant of the method, the nucleation centers are formed at the points where the gas bubbles are intended to form and the nucleation centers are characterized by the fact that - for example, by means of a point of greater topographic roughness or uneven chemical homogeneity of the surface - locally, in a defined location, the activation energy to form a gas bubble decreases.
[00305] The retention of a layer of gas submerged in liquid, for example, submerged in water, is of great technical interest. There is great potential for use for surfaces of this type, for example, in the field of ship coverings, among others, to reduce friction and obtain anti-fouling effects.
[00306] These surfaces are already produced in scale in the laboratory. Among others, the Salvinia effect, the hierarchical structuring based on the example of Notonecta, and the effects of shark skin and dolphin skin were successfully implemented.
[00307] The problem, however, is that (i) air escapes at the edges of the coating, and (ii) in the case of large surfaces covered with layers of gas, there are generally considerable pressure differentials between different points in the layer. An example is a vertical wall submerged in water. Thanks to hydrostatic pressure, which increases linearly with the depth of the water, different points on the surface are subjected to different static pressures. If the surface is equipped with a gas retaining layer and is therefore covered by a layer of gas submerged in liquid, the gas will be forced from regions of high pressure to regions of low pressure. A homogeneous thickness gas layer, therefore, is not formed and - even more seriously - the gas layer in the relatively high pressure zones will ultimately escape. (iii) a corresponding problem also exists if pressure gradients in the layer are not based on hydrostatic pressure but on dynamic pressure differentials, for example, thanks to different flow rates of the surrounding liquid at different locations on the surface. (iv) The problem also consists of the reversible and also retroactive and economical application of partially complex surface structures. (v) There is also a desire for a simple means to carry out regeneration or - ideally - self-regeneration of the air layer.
[00308] In the method and device according to the invention, instead of a continuous air layer or compartments of air layers, an arrangement of individual air bubbles is used, which preferably form at desired locations of a way induced by surface structures. For this, a device is produced and used to retain a layer of air submerged in water or, more generally, a layer of gas submerged in liquid, characterized by the fact that the gas layer is not continuous, but in the form of a matrix of small gas bubbles at predefined points on the surface, in a preferred embodiment configured so that the gas bubbles form at predefined points on the surface which, by topographic structure and / or by the chemical functionalization of the surface, demonstrate energy preference for the stabilization of gas bubbles, in which, in a preferred variant of the method, the nucleation centers are formed at the points where the gas bubbles are intended to form and the nucleation centers are characterized by the fact that - for example, by means of a point of greater topographic roughness or non-chemical homogeneity of the surface - locally decrease, in a defined location, the activation energy to form air a gas bubble.
[00309] In a variant of the aforementioned device, area elements (which are the subject of an invention deposited in parallel) with the above-mentioned surface properties and which can be applied to the surface, for example, outside ships or inside pipes, albeit retroactively, for example, by adhesive bonding.
[00310] Other Variants or characteristics refer to • application in the form of boards, boards etc. with the desired surface properties. • application of flexible area elements. • application by reversible or irreversible adhesive bonding. • coating of ship surfaces, in whole or in part. • use of metallic surface structures. • use of surfaces with a continuous air layer. • use of surfaces that form, develop or retain only a regular or irregular pattern of gas bags or gas bubbles submerged in liquid. • use of the aforementioned pattern of gas bags or gas bubbles submerged in liquid as a form of "ball bearing made of gas or air" - for mechanical orientation and / or reduction of friction. • use as a liner on ships, in ducts flow tubes, tubes and chemical reaction vessels.
[00311] Device to retain a layer of air submerged in water or, more generally, a layer of gas submerged in liquid, characterized by the fact that the layer of gas submerged in liquid is formed autonomously, that is, there is no need to introduce a layer of air submerged in water, instead the continuous or discontinuous gas layer (this is in the form of gas bubbles on the surfaces) is formed on its own, for example, by the use of gas molecules dissolved in the liquid or by evaporation of liquid at negative pressure, characterized by the fact that, by topographic and / or chemical structuring, regions are produced in which the entry of liquid would consume such a high level of surface energy that regions without liquid submerged in liquid are formed against it (“air bags”) - in a variant of the method, by periodic or non-periodic placement on the surface of capillaries or pins of specific shape, preferably dehumidifying or other capillaries and structures that form an open or closed “crown” that completely or partially surround the gas bubble that forms.
[00312] The retention of a layer of gas submerged in liquid, for example, submerged in water, is of great technical interest. There is great potential for use for surfaces of this type, for example, in the field of ship coverings, among others, to reduce friction and obtain anti-fouling effects.
[00313] These surfaces are already produced in scale in the laboratory. Among others, the Salvinia effect, the hierarchical structuring based on the example of Notonecta, and the effects of shark skin and dolphin skin were successfully implemented.
[00314] The problem is that, in adverse operational conditions (wave surge, wave impact in the case of ship coverings etc.) or for relatively long periods of time, the loss of local or extensive gas, partial or total, occurs in certain places or as a whole.
[00315] Subsequent artificial refilling or refilling of the gas is inconvenient, requires monitoring and requires suitable and possibly expensive apparatus for filling and monitoring and even a filling installation for each compartment in the case of a structure in compartments of the air layer , and even a filling installation for each gas bubble in the case of a structure with gas bubbles.
[00316] In the method and device according to the invention, said problem is solved because a device is used to retain a layer of air submerged in water or, more generally, a layer of gas submerged in liquid, characterized by the fact that that the gas layer submerged in liquid forms autonomously, that is, there is no need to introduce a gas layer submerged in water, instead the continuous or discontinuous gas layer (this is in the form of gas bubbles on the surfaces ) is formed on its own, for example, by the use of gas molecules dissolved in the liquid or by evaporation of the liquid at negative pressure, characterized by the fact that, by topographic and / or chemical structuring, regions are produced in which the introduction of liquid would consume a level of surface energy so high that regions without liquid submerged in liquid form on their own (“air pockets”) - in a variant of the method, due to the periodic or non-periodic disposition in the surface of capillaries or pins of a specific shape, preferably dehumidifying capillaries or other structures that form an open or closed "crown" that surrounds all or part of the gas bubble that forms.
[00317] In a variant of the aforementioned device, area elements (which are the subject of an invention deposited in parallel) with the above-mentioned surface properties and which can be applied to the surface, for example, outside ships or inside pipes, albeit retroactively, for example, by adhesive bonding.
[00318] Other Variants or characteristics refer to the combination of • self-loading above the gas layer with other devices to artificially refill or refill the gas layer, for example, capillaries, membranes, textiles etc. • device as described immediately above, possibly also coupled with measurement and / or control and / or regulation devices that measure and control the condition of the gas layer as a whole or in a spatially resolved manner and automatically trigger the refueling, if necessary. • application in the form of boards, boards, etc. with the desired surface properties. • application of flexible area elements. • application by reversible or irreversible adhesive bonding. • coating of ship surfaces, in whole or in part. • use of metallic surface structures. • use of surfaces with a continuous air layer. • use of surfaces that form, develop or retain only a regular or irregular pattern of gas bags or gas bubbles submerged in liquid. • use of the aforementioned pattern of gas bags or gas bubbles submerged in liquid as a form of "ball bearing made of gas or air" - for mechanical orientation and / or reduction of friction. • use as a liner on ships, in ducts flow tubes, tubes and chemical reaction vessels.
[00319] Device to retain air or gas bubbles (“air bags”) submerged in liquid, characterized by the use of capillaries with open or closed crown structure or groups of simple capillaries curved directly on the surface so that the capillaries, as a group, form a crown, that is, an open “vessel” in which air or gas bubbles are closed and retained safely submerged in liquid even in the flowing medium or against the action of fluctuation - in a preferred embodiment, with the capillary surfaces being provided with a hydrophobic or super-hydrophobic surface or surface coating, also preferably with elastic capillaries which, under mechanical load, can deform together with the gas bubble, in addition - in a variant of the invention - the use of gas bubbles in the crown as nucleation centers for autonomous or artificial refilling of a gas layer coming from gas bubbles in the crown.
[00320] The retention of a layer of gas submerged in liquid, for example, submerged in water, is of great technical interest. There is great potential for use for surfaces of this type, for example, in the field of ship coverings, among others, to reduce friction and obtain anti-fouling effects.
[00321] These surfaces are already produced in scale in the laboratory. Among others, the Salvinia effect, the hierarchical structuring based on the example of Notonecta, and the effects of shark skin and dolphin skin were successfully implemented.
[00322] One problem is the controlled nucleation and retention of individual gas bubbles at a defined location, and their retention ensured with respect to external forces.
[00323] In the method and device according to the invention, a device is produced and used to retain air or gas bubbles ("air pockets") submerged in liquid, characterized by the use of capillaries with a structure in form of an open or closed crown or groups of simple capillaries curved directly on the surface so that the capillaries, as a group, form a crown, that is, an open “vessel” in which air or gas bubbles are closed and safely retained submerged in liquid even in the flowing medium or against the float action - in a preferred embodiment, with the capillary surfaces provided with a hydrophobic or super-hydrophobic surface or coating, also preferably with elastic capillaries which, under mechanical load, can deform together with the gas bubble, in addition - in a variant of the invention - to the use of gas bubbles in the crown as nucleation centers for autonomous or artificial refilling of a layer of gas from gas bubbles in the crown.
[00324] In a variant of the method, open or closed crowns are used, located not directly on the surface but at the end of a multi-core or forked stem (open or closed “egg beater structure”).
[00325] In another variant of the aforementioned device, area elements (which are the subject of an invention deposited in parallel) with the aforementioned surface properties and which can be applied to the surface, for example, outside ships or inside pipes, albeit retroactively, for example, by adhesive bonding.
[00326] Other Variants or characteristics refer to • use of capillaries or elastic structures to form the crown structure. • use of capillaries or crowns with surfaces that are entirely or partially hydrophobic or super-hydrophobic or entirely or partially provided with a hydrophobic or super-hydrophobic coating. • use of open or closed crown structures. • use in conjunction with a gas retention sub-tarpaulin layer ("aerenchyma"). • production of crown structures from polymers, metals or ceramic materials. • production of crown structures by molding master structures and / or by three-dimensional laser structuring or production of master structures by three-dimensional laser structuring or laser lithography and then molding of said structures without or after an inversion process . • combination of self-loading above the gas layer with other devices to artificially refill or refill the gas layer, for example, capillaries, membranes, textiles etc. • device as described immediately above, possibly also coupled with measurement and / or control and / or regulation devices that measure and control the condition of the gas layer as a whole or in a spatially resolved manner and automatically trigger the refueling, if necessary. • application in the form of boards, boards, etc. with the desired surface properties. • application of flexible area elements. • application by reversible or irreversible adhesive bonding. • coating of ship surfaces, in whole or in part. • use of metallic surface structures. • use of surfaces with a continuous air layer. • use of surfaces that form, develop or retain only a regular or irregular pattern of gas bags or gas bubbles submerged in liquid. • use of the aforementioned pattern of gas bags or gas bubbles submerged in liquid as a form of "ball bearing made of gas or air" - for mechanical orientation and / or reduction of friction. • use as a liner on ships, in ducts flow tubes, tubes and chemical reaction vessels.
[00327] Device for retaining a layer of air submerged in water or, more generally, a layer of gas submerged in liquid, characterized by the fact that, under the layer that retains air, based on the example of Notonecta glauca or Salvinia annoying, for example, a hydrophobic or super-hydrophobic porous, microporous or nanoporous layer is located that can act as air storage in case of mechanical load on the air layer, in such a way that the air layer is not released, but yes forced into the air storage layer and, after the load ceases to act, released in part or in whole again.
[00328] The retention of a layer of gas submerged in liquid, for example, submerged in water, is of great technical interest. There is great potential for use for surfaces of this type, for example, in the field of ship coverings, among others, to reduce friction and obtain anti-fouling effects.
[00329] These surfaces are already produced in scale in the laboratory. Among others, the Salvinia effect, the hierarchical structuring based on the example of Notonecta, and the effects of shark skin and dolphin skin were successfully implemented.
[00330] The problem is that, in adverse operational conditions (wave surge, wave impact in the case of ship coverings etc.) or for relatively long periods of time, the loss of local or extensive gas, partial or total, occurs in certain places or as a whole.
[00331] Subsequent artificial refilling or refilling of the gas is inconvenient, requires monitoring and requires suitable and possibly expensive equipment for filling and monitoring and even a filling installation for each compartment in the case of a structure in compartments of the air layer , and even a filling installation for each gas bubble in the case of a structure with gas bubbles.
[00332] In the method and device according to the invention, the loss of air in the case of pressure loads acting on the layer is prevented by including protective removal facilities for the air. This is achieved by using a device to retain a layer of air submerged in water or, more generally, a layer of gas submerged in liquid, characterized by the fact that, under the layer that retains air, based on the example of Notonecta glauca or Salvinia molesta, for example, a hydrophobic or super-hydrophobic porous, microporous or nanoporous layer is located which can act as air storage in case of mechanical load on the air layer, such that the air layer does not be released, but forced into the aerenchyma and, after the load ceases to act, another is released.
[00333] In another variant of the aforementioned device, area elements (which are the subject of an invention deposited in parallel) with the above-mentioned surface properties and which can be applied to the surface, for example, outside ships or inside pipes, albeit retroactively, for example, by adhesive bonding.
[00334] Other Variants or characteristics refer to the use of an air storage layer in the form of a dense arrangement of capillaries or thin wires in the form of a "skin". • use of an air storage layer in the form of a dense array of capillaries or thin wires in the form of a felt or fiber network with disordered or, preferably, oriented fibers. • use of an air storage layer, as described immediately above, in which the felt or net is constructed with textile fibers or metallic wires. • use of an air storage layer in the form of a porous, microporous or nanoporous material. • use of an air storage layer, as described immediately above, where the porous material is a polymer or a metal or ceramic material. • use of an air storage layer, as described immediately above, where the porous material is a layer of polymer mixture from which one of the polymer components has been removed by means of a selective solvent - preferably after the forming process of the layer with concomitant phase separation - thus a porous layer was produced which then - with or without additional hydrophobization of the internal porous surfaces and / or the surface of the layer - acts as air storage. • use of a precursor for the production of a metallic or ceramic layer as one of the two components and production of that porous metallic or ceramic layer by subsequent heat treatment. • application in the form of boards, boards, etc. with the desired surface properties. • application of flexible area elements. • application by reversible or irreversible adhesive bonding. • coating of ship surfaces, in whole or in part. • use of metallic surface structures. • use of surfaces with a continuous air layer. • use of surfaces that form, develop or retain only a regular or irregular pattern of gas bags or gas bubbles submerged in liquid. • use of the aforementioned pattern of gas bags or gas bubbles submerged in liquid as a form of "ball bearing made of gas or air" - for mechanical orientation and / or reduction of friction. • use as a liner on ships, in ducts flow tubes, tubes and chemical reaction vessels.
[00335] Ball bearing composed of air or gas balls: reduction of the friction of surfaces submerged in liquid by the coating or partial coating with an arrangement of gas bubbles, preferably in "air pockets", niches or fixing means that they are preferably of an energy aspect and which are fixed against the highlight and which can be located directly on the surface, but which, in turn, can be located at the end of a capillary or stem or compact spring bundle or other means of retention, and the formation of rotating, anti-friction and smooth bearings submerged in liquid from gas bubbles of this type, in which the fixed gas bubbles perform the function of the balls in ball bearings. conventional spheres - with the advantages of self-refilling, absence of wear and, therefore, unlimited service life depending on mechanical abrasion, and with additional advantages regarding the absence of abraded particles (which must be maintained) suspended, lead to additional mechanical wear, can settle and form solid sediments that can limit the service life of moving mechanical components) and the absence of lubricants (oils etc. undergo aging, must be replaced, are poisonous and incompatible with living organisms, and must be eliminated).
[00336] The development of bearings, for example, rolling, anti-friction and flat, with long service life, low wear and low friction and in which, in particular, the adhesive friction when starting and the damage to the bearing during long stationary periods are eliminated, it is a technical challenge. Magnetic bearings are expensive and cannot be used in all ambient conditions.
[00337] In particular, under liquids, especially if they are corrosive liquids (like salt water) or chemically aggressive (acids, brines, oxidizers), there is a real technical problem.
[00338] In the method and device according to the invention, the problem is solved by the use of ball bearings, anti-friction and planes composed of air or gas bubbles and arrangements of these spheres (in the case of plain bearings, for example , of flat surfaces that are coated with said spheres composed of gas submerged in liquid (gas bubbles)): a reduction in friction of surfaces submerged in liquid is obtained by coating or partial coating with an arrangement of gas bubbles, preferably in “air pockets”, niches or fixation means that are preferably of an energy aspect and are fixed against the highlight and which can be located directly on the surface, but which, themselves, can also, by their very nature. instead, be located at the end of a capillary or a compact spring rod or bundle or other retention means, and the formation of rotating, anti-friction and smooth bearings submerged in liquid from gas bubbles of said t ipo, in which the fixed gas bubbles perform the function of spheres in conventional ball bearings - with the advantages of self-refilling, no wear and therefore unlimited service life depending on mechanical abrasion, and with additional advantages the absence of abraded particles (which must be kept in suspension, lead to additional mechanical wear, can settle and form solid sediments that can limit the service life of moving mechanical components) and the absence of lubricants (oils etc. undergo aging, must be replaced, are poisonous and incompatible with living organisms, and must be eliminated).
[00339] Other Variants or characteristics refer to the use of • a layer of persistent gas or compartments composed of layers of gas that are retained on the surface, instead of the individual gas spheres (gas bubbles). • use of pinned gas bubbles positionally fixed. • use of non-pinned and non-positionally fixed gas bubbles that can move in a defined environment, similar to “normal” ball bearing spheres, movable inside and possibly together with their ball cage. • combination with facilities to load the gas layer or the gas spheres (“refueling”), in the case of gas loss, by means of additional devices to artificially refill or refill the gas layer, for example, capillaries, textile membranes etc., • device as described immediately above possibly also coupled with measurement and / or control and / or regulation devices that measure and control the condition of the gas layer as a whole or in a spatially resolved manner and automatically trigger refueling, if necessary . • application in the form of boards, boards, etc. with the desired surface properties. • application of flexible area elements. • application by reversible or irreversible adhesive bonding. • coating of ship surfaces, in whole or in part. • use of metallic surface structures. • use of surfaces with a continuous air layer. • use of surfaces that form, develop or retain only a regular or irregular pattern of gas bags or gas bubbles submerged in liquid. • use of the aforementioned pattern of gas bags or gas bubbles submerged in liquid as a form of "ball bearing made of gas or air" - for mechanical orientation and / or reduction of friction. • use as a liner on ships, in ducts flow tubes, tubes and chemical reaction vessels.
[00340] Chemical reaction vessels, tubes and ducts with walls composed of air: chemical reaction vessels of stable format for reactions of liquids or liquids with included solid components and particles, characterized by the fact that the walls of the reaction vessel - which, in a preferred conceptual variant, are dimensionally stable and dimensionally defined - are composed of a layer of air or gas generated by means of a solid vessel wall lined with structures for the retention of gas submerged in liquid, and use of these devices for carrying out chemical reactions and physical and chemical processes, in one variant of the method with additional use of the gas layer for feeding reaction reagents or for the discharge of reaction products, in another variant of the method for using the gas for cleaning and flushing with gas, for monitoring the pressure in the reaction vessel, for the discharge or supply of thermal energy, or for a combination of these.
[00341] The provision of reaction vessels suitable for reactions under extreme conditions, high temperatures and with chemically reactive liquid media places high demands on the vessel walls.
[00342] Another problem is that, after coming in contact with a liquid, the walls of the vessel must generally be cleaned in an inconvenient way before another liquid enters the vessel or crosses the line. This is especially true in the case of foodstuffs. After transporting toxic liquids to a vessel or pipe, they must be cleaned carefully before being filled with liquid foodstuffs such as drinks, milk, etc.
[00343] In the method according to the invention and device according to the invention, the mentioned problems are solved because the walls of the vessel do not make contact with the liquid and, therefore, it is also not possible for liquid residues to remain on the walls of the vessel , and it is also not possible for chemical reactions to occur between the liquid and the vessel walls because a layer of persistent gas is introduced between the liquid and the vessel wall. In fact, "chemical reaction vessels, tubes and ducts with walls composed of air" are used: Chemical reaction vessels of stable shape are used for reactions of liquids or liquids with included solid components and particles, characterized by the fact that that the walls of the reaction vessel - which, in a preferred conceptual variant, are dimensionally stable and dimensionally defined - are composed of an air or gas layer generated by means of a solid vessel wall lined with structures for the retention of gas submerged in liquid,
[00344] The use of these devices for carrying out chemical reactions and physical and chemical processes is also claimed, in a variant of the method with additional use of the gas layer for feeding reaction reagents or for the discharge of reaction products,
[00345] Another variant of the method involves using the gas layer for cleaning and discharging with gas, for monitoring the pressure in the reaction vessel, for the discharge or supply of thermal energy, or for a combination of these.
[00346] Other Variants or characteristics refer to the use of • a layer of persistent gas or compartments composed of layers of gas that are retained on the surface, instead of the individual gas spheres (gas bubbles). • use of pinned gas bubbles positionally fixed. • use of non-pinned and non-positionally fixed gas bubbles that can move in a defined environment, similar to “normal” ball bearing spheres, movable inside and possibly together with their ball cage. • combination with facilities to load the gas layer or the gas spheres (“refueling”), in the case of gas loss, by means of additional devices to artificially refill or refill the gas layer, for example, capillaries, textile membranes etc., • device as described immediately above possibly also coupled with measurement and / or control and / or regulation devices that measure and control the condition of the gas layer as a whole or in a spatially resolved manner and automatically trigger refueling, if necessary . • application in the form of boards, boards, etc. with the desired surface properties. • application of flexible area elements. • application by reversible or irreversible adhesive bonding. • coating of internal and external surfaces - in whole or in part. • use of metallic surface structures. • use of surfaces with a continuous air layer. • use of surfaces that form, develop or retain only a regular or irregular pattern of gas bags or gas bubbles submerged in liquid. • use of the aforementioned pattern of gas bags or gas bubbles submerged in liquid as a form of "ball bearing made of gas or air" - for mechanical orientation and / or reduction of friction. • use as a liner on ships, in ducts flow tubes, tubes and chemical reaction vessels.
[00347] Structured underwater air retention surfaces with air retention in the form of “air layers”, “air compartments” and “air pockets”: continuous air layers, air compartments with limited area extension and bubbles and local air pockets and the irregularly structured variant with continuous transition between these cases.
[00348] Gas layers on surfaces submerged in liquid are of great technological interest for reducing friction in the case of ships and pipes and for protecting the surface against fogging, (bio) encrustation, corrosion and chemical attack. .
[00349] By structuring suitable surfaces, it is possible for a layer of gas or gas bubbles, which adheres to the surface, to be submerged in liquid. The problem is to find suitable surface structures that, even in the case of pressure fluctuations, retain the continuous or discontinuous gas layer submerged in liquid permanently or at least for certain periods of time.
[00350] These problems are solved by a hydrophobic or super-hydrophobic surface that is topographically structured so that the gas layer or gas bubbles are retained and, in a preferred variant, additionally prevented from escaping by hydrophilic pins, and / or, in the case of gas bubbles, certain topographically preformed regions, "air pockets", in the surface structure are created that allow for the stable storage of small volumes of gas submerged in liquid in a stable manner. In this case, it is possible to make use of rugged surfaces even in the scale of millimeters, micrometers, nanometers or a combination of several length scales in order, thus, to realize super-hydrophobic characteristics through nanorrugosity and to realize the air pockets by through the roughness in the millimeter and micrometer range, said air pockets preferably having typical dimensions in the range between 10 μm and 5 mm, particularly preferably between 0.1 mm and 3 mm. Said air pockets can then, similarly, in a preferred variant, have hydrophilic pinning centers on their surface otherwise hydrophobic or super-hydrophobic in order to safely retain the air-water interface and thus prevent leakage of gas bubbles.
[00351] In this case, pinning can also occur in several structuring planes (hierarchical pinning or pinning effect in two levels or in several levels) or in irregularly structured surfaces even with a continuous hierarchy (which corresponds to an infinite number hierarchical plans). Here, in the case of pinning occurring in the upper hierarchical panels, regions covered with extensive air can form, with coherent and even continuous layers of air being formed above a so-called percolation limit; only when the air escapes somewhere and the water reaches the lower hierarchical planes, separate volumes of air separated in a mutually spatial way are formed on the surface (“compartment structure”) even, in the case of yet another water entry, for example thanks to very high pressure fluctuations, even more air is lost and finally only the air pockets remain as the final air reservoir. These air pockets, then, have a triple function: • They serve as a final air reservoir that can only be eliminated with difficulty, as an “emergency air reservoir”. • They, however, protect most, usually 60% to 98% of the entire surface, against oxidation, chemical attack or (bio) encrustation and have an action to reduce friction, and above all: • They act as cores for restoring the air layer, both in the case of active refilling of the gas layer (“replenishment”) and in the process of self-regeneration of the air layer.
[00352] This structuring directed in several planes, or scales of length and possibly also scales of height, and - in a preferred variant - additionally hierarchical pinning exhibit the said three stages of air retention in the simplest case: 1. Air layer continuous, supported and supported only by individual support structures (capillaries, pillars, elevations) that can be hydrophobic or super-hydrophobic with or without hydrophilic pinning centers (these, if present, preferably at the upper end of said support structures) . The friction between the liquid and the solid body is thus massively reduced, in part to less than 5% of the value without an air layer. However, in this condition (which is virtually ideal for all other technical properties), the susceptibility to air loss in the event of pressure fluctuations is high. The activation barriers with respect to air loss - for example, by escaping gas bubbles - are relatively low in relation to the force required per unit area or in relation to the energy required per unit area. 2. In the event of air loss, stage 1 (condition as described immediately above) passes to stage 2: Coherent and relatively large regions covered with air are formed from the surface submerged in liquid, but the percolation limit for air layers continuous drops. The individual surface regions covered with air are bounded by partitions or by surface regions not covered with air that make contact with water and that generally prevent gas exchange between different islands or air compartments. In this condition, the reduction in friction remains significant, but it is considerably less compared to stage 1. The protection of surfaces against contact with water or liquid still remains substantially whole or at least for the most part (usually, only a maximum of 2% to 10% of the entire surface makes contact with water). The activation limit required for detaching air from the layer, or, more generally, gas from the layer, is significantly higher than in stage 1. 3. In the case of yet another gas loss, for example, due to very intense pressure oscillations, the final final stage is stage 3, in which the surface stores only small volumes of air in hydrophobic niches, called air pockets. These also have hydrophilic pinning centers on their side facing the water. The action of reducing the friction of the air layer is significantly weakened in this condition in relation to stage 1 and, in extreme cases, ceases to exist. However, even in stage 3, depending on the topographic configuration, a considerable reduction in the contact area between the surface of the submerged solid body and the water is obtained, usually by a factor greater than 10, that is, only less than 10% of the surface. make direct contact with water, or, more generally, with liquid, in relation to the condition without “air pockets” filled with gas.
[00353] Of course, air can be replaced, very generally, by any desired gas. Water can also be replaced with any other desired liquid. “Hydrophobic or super-hydrophobic” must then be replaced by “dehumidifying or super-dehumidifying in relation to said liquid” (defined, very similarly to hydrophobic and super-hydrophobic, by means of the corresponding contact angle), and the pins hydrophilic should be replaced by “liquidophilic” pins, that is, humectants, in relation to that liquid. In this case, relatively small differences are sufficient: “Hydrophilic pins” do not necessarily have to be really hydrophilic in the sense of dictionary definition; in some cases, it is enough that they are merely more humectants than another hydrophobic surface (or, more generally, for any desired liquid: "liquidophobic").
[00354] In variants of the embodiment, it is also possible to provide that the three hierarchical plans of the structuring are not included (only one plan is included) or that two plans or all three plans are included, or, instead of a regular structured surface or semi-regular, a randomly structured surface can be included with some roughness and with relatively small or relatively large pinout centers in certain places and whose natural depressions serve as air pockets. Furthermore, suitable as surfaces of specific roughness, they are certainly porous surfaces whose pores located on the surface can serve as air pockets.
[00355] A particular variant of such a surface is fibers or textile fibers which, thanks to a surface configured as described above, can retain a continuous or discontinuous layer of air submerged in water. Everything is as described immediately above, the only exception being that the structured surface described now is the surface of a fiber. It can also be structured again - like the surfaces already described above - • by regular or irregular topographic structure or • by regular or irregular chemical structure (that is, spatially dependent chemical or biochemical surface functionalization) or • by surface roughness or • by surface porosity or by a combination of the shapes mentioned, and may or may not have hydrophilic pinning centers. With regard to fibers that retain gas on their surface submerged in liquid, it is of interest that it is possible to build or produce textiles, fabrics, knitwear, carpets, tapes, ropes, felts, bathing suits (swimming trunks, bath etc.) etc. that retain gas on their surface submerged in liquid. It is also conceivable that ships, boats, aquatic sports devices (including surfboards etc.), buoys, drilling platforms, measuring stations, measuring devices, components exposed to water from marine wind stations, other structures in water etc. are coated with said air retention textiles, for example, in order to obtain friction reduction, anti-fouling action or corrosion prevention.
[00356] Uses of the Salvinia effect: • Non-contact vessels for highly reactive liquids. • Liquids surrounded by an air cushion from a reaction partner to which the gas or a gas constituent in the form of fine droplets or fine particles can be fed. • Use of the air cushion for thermal insulation. • Use of the air cushion to reduce friction. • Use of the airbag to obtain anti-fouling effect. • Use of the airbag to prevent the formation of biofilm. • The anti-fouling action of the capillaries and the substrate surface itself could be obtained by coating with bactericides, fungicides, nano-silver, nanocopper and components containing silver and components containing copper. • Use of the air cushion for electrical isolation and galvanic separation, especially in the case of electrolytes.
[00357] Lasting obtaining of the Salvinia effect by means of refillable air layers: • Recharge of the air layer by means of pumps or gas bottles pressurized through thin nozzles or through a gas-permeable surface between the different capillaries. • Recharge of the air layer by galvanic, catalytic, photocatalytic or galvanocatalytic decomposition of the liquid medium (for example, water). • Recharge of the air layer by means of gaseous components dissolved in the liquid, thanks to the surface energy of the water that increases to a degree such that it is kept away and thus the sum of the partial pressures of all gases and liquids in the liquid medium is equal to the gas pressure in the Salvinia gas layer - which may mean that it is less than the hydrostatic pressure in the liquid, and • targeted use of this effect in order to increase the activation energy for the formation of gas bubbles: o liquid medium is still “attracted” to the surface of the leaf capillaries thanks to the negative pressure in the gas layer.
[00358] Generation of layers of air with or without Salvinia effect:
[00359] Use, among others, for: • Air retention. • Friction reduction. • Fluctuation. • Anti-fouling. • Corrosion prevention. • Adhesion prevention - production of non-stick surfaces by “air coating” as described. • In combination with self-recharge or active recharge of the air layer, it would be possible, in this case, to build a highly efficient system for reducing friction. • Additional friction reduction would be accomplished by non-polar Teflon gliders at the end of capillaries. • By making the angle of inclination of the upper extremities of the capillaries shallower, the derivative of the wetting energy in relation to the depth of water penetration into the capillary layer and, therefore, the repellent force with which the liquid is repelled when it enters increases massively . • The elasticity of the angled capillaries must, in addition, by selecting the elastic constant, ensure that the capillary bends instead of being moistened by the liquid.
[00360] Figure 27a illustrates a gas retention layer with a single stage protrusion system, in which all protrusions have substantially the same longitudinal extent.
[00361] Figure 27b illustrates a gas retention layer with a system of double stage protuberances, in which the protuberances are divided into short and long.
[00362] Figure 28 illustrates a gas retention layer formed by an uneven surface, in which the surface roughness can have a length scale of about 10 μm to about 3 mm.
[00363] Figure 29a illustrates a gas retention layer with an uneven surface in the form of a single stage system. Figure 29b illustrates a gas retaining layer with an uneven surface in the form of a double stage system. Fig. 29c illustrates a gas retaining layer with an uneven surface in the form of a triple stage system.
[00364] Figure 30a illustrates a gas retention layer formed by a filiform element. Fig. 30b illustrates a filiform or fiber-like element with a gas retention layer in the form of a double stage system.
[00365] Figure 31 illustrates a gas retention layer formed on a filiform element and with a super hydrophobic surface on which hydrophilic points or pins are optionally formed.
[00366] Figure 32 illustrates a gas retention layer formed on a filiform element, in which different configurations of surfaces are illustrated.
[00367] Figure 33 illustrates a gas retention layer formed on a filiform element, in which the gas retention layer has an annular structure. List of reference numbers 2 - Wall 4 - Liquid 5 - Gas 6 - Surface cover 10 - Gas retaining layer 10c - Base of the gas retaining layer 10 12 - Gas permeable tarpaulin 14 - Gas supply device 16 - Gas duct 18 - Gas source 20 - Valve 22 - Regulation device 24 - Sensing device 26 - Protruding element 27 - Protruding element 28 - Gas discharge device 30 - Depression 32 - Opening of the depression 30 34 - Hydrophobic coating of depression 30 36 - Surface coating 38 - Rugged surface 40 - Fiber 42 - Partition 10 44 - Sub-region of the gas retention layer A - Gas discharge direction L - Longitudinal direction

权利要求:
Claims (18)
[0001]
1 - Use of a gas retention layer (10) that is arranged in a body (2) that can be submerged in liquid or wetted by the liquid, and that is in contact through a side facing the liquid (10a) with the liquid (4) when the body (2) is submerged in / wetted by the liquid (4), as corrosion prevention and / or anti-fouling and / or prevention of contamination of the liquid with poisonous substances contained on the side facing the liquid (10a) of the body (2) and / or friction reduction, characterized by the fact that the gas retention layer (10) has on the side facing the liquid (10a), recesses (30) or protruding elements (26 , 27), whose surfaces are hydrophobic at least regionally, and a gas layer (5) that is retained in the submerged / wet region of the gas retention layer (10) and separates the liquid (4) and the submerged / wet region of the body (2) from each other at least regionally, and in which the gas retention layer (10) is divided into a plurality of subregions (44) p or fluid-impermeable partitions (42).
[0002]
2 - Use of the gas retention layer (10), according to claim 1, characterized by the fact that a corrosion prevention coating and / or an anti-fouling coating is disposed between the gas retention layer (10 ) and the body wall (2), and where the gas retaining layer (10) separates the corrosion prevention coating and / or the anti-fouling coating from the liquid (4) at least regionally.
[0003]
3 - Use of the gas retention layer (10), according to claim 1 or 2, characterized by the fact that the fluid-impermeable partitions (42), which are of equal length, are arranged so as to form subregions (44) hexagonal, or fluid impermeable partitions (42) are arranged to form subregions (44) in the form of elongated honeycombs.
[0004]
4 - Use of the gas retention layer (10), according to any of the preceding claims, characterized by the fact that the partitions (42) are hydrophilic in shape at least regionally.
[0005]
5 - Use of the gas retention layer (10), according to any one of the preceding claims, characterized by the fact that the protruding elements (26, 27) are present in all subregions (44).
[0006]
6 - Use of the gas retention layer (10) that is arranged in a body (2) that can be submerged in liquid or wetted by the liquid, and that is in contact through a side facing the liquid (10a) with the liquid (4) when the body (2) is submerged in / wetted by the liquid (4), as corrosion prevention and / or anti-fouling and / or prevention of contamination of the liquid with poisonous substances contained on the side facing the liquid (10a) of the body (2) and / or friction reduction, characterized by the fact that the gas retention layer (10) has on the side facing the liquid (10a), recesses (30) or protruding elements (26, 27), whose surfaces are hydrophobic at least regionally, and a gas layer (5) that is retained in the submerged / wet region of the gas retention layer (10) and separates the liquid (4) and the submerged / wet region from the body (2) from each other at least regionally, and that the protruding elements (26, 27) have a central surface region (26e, 27e) that is h idrophilic and that is surrounded by a region of hydrophobic surface of the protruding elements (26, 27).
[0007]
7 - Use of the gas retention layer (10), according to any of the preceding claims, characterized by the fact that the gas retention layer (10) is charged with gas from one side facing the body ( 10b), located opposite the liquid side (10a) of the gas retaining layer (10).
[0008]
8 - Use of the gas retention layer (10), according to any of the preceding claims, characterized by the fact that a gas-permeable layer (12) is arranged on the side facing the body (10b) of the gas layer gas retention (10).
[0009]
9. Use of the gas retention layer (10) according to claim 8, characterized in that the gas-permeable layer (12) is in the form of a liquid impermeable layer and / or a hydrophobic layer.
[0010]
10 - Use of the gas retention layer (10), according to claim 8 or 9, characterized by the fact that a gas supply device (14) is connected to the gas permeable layer (12) in such a way that gas (5) flows from a gas supply device (14) to the gas retaining layer (10) through the gas permeable layer (12).
[0011]
Use of the gas retention layer (10) according to any one of claims 8 to 10, characterized in that the gas-permeable layer (12) is in the form of a porous semipermeable membrane.
[0012]
12 - Use of the gas retention layer (10), according to claim 10 or 11, characterized by the fact that the gas supply device (14) is in the form of a gas permeable layer that is arranged on the side facing the body of the gas-permeable layer (12).
[0013]
13 - Use of the gas retention layer (10) according to any one of claims 1 to 6, characterized in that the gas retention layer (10) is charged with gas from the side facing the liquid (10a) of the gas retaining layer (10).
[0014]
14 - Use of the gas retention layer (10), according to claim 13, characterized by the fact that at least one gas discharge device (28) is provided, which has a gas discharge opening on the side facing the liquid (10a) of the gas retaining layer (10); and in which a gas supply device (14) is provided, which connects to the gas discharge device (28), in which the gas supplied by the gas supply device (14) flows out of the discharge device gas (28) and is received at least partially in the gas retention layer.
[0015]
15 - Use of the gas retention layer (10) according to claim 14, characterized by the fact that the gas discharge device (28) extends through the gas retention layer (10).
[0016]
16 - Use of the gas retention layer (10) according to any one of the preceding claims, characterized in that the surface structure of the gas retention layer (10) comprises a material selected from polymers, lacquers , ceramics and metals.
[0017]
17 - Use of the gas retention layer (10), according to claim 16, characterized by the fact that the gas retention layer (10) is composed of a lacquer or embossed plastic resin.
[0018]
18 - Use of the gas retention layer (10), according to any of the preceding claims, characterized by the fact that the body (2) is in the form of tiles, sheets, balls, or walls of vessels, tubes or ships .

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同族专利:

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ES2842502T3|2021-07-14|

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CN106984510B|2021-01-29|

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EP2822704B1|2020-11-11|

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DK2822704T3|2020-12-21|

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CA3114548A1|2013-09-12|

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CA2866082A1|2013-09-12|

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KR102356570B1|2022-02-08|

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US20150273791A1|2015-10-01|

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CA2866082C|2021-06-22|

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PT2822704T|2021-01-07|

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US9630373B2|2017-04-25|

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JP6270745B2|2018-01-31|

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US20170203822A1|2017-07-20|

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CN106984510A|2017-07-28|

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WO2013131618A3|2013-10-31|

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CN104271259B|2016-09-28|

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US20200216424A1|2020-07-09|

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JP6715821B2|2020-07-01|

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EP2822704A2|2015-01-14|

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KR20190116531A|2019-10-14|

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KR102210224B1|2021-02-01|

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DE112013001273A5|2014-12-11|

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KR102028621B1|2019-10-04|

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KR20150008048A|2015-01-21|

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JP2018094925A|2018-06-21|

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WO2013131618A2|2013-09-12|

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KR20210013328A|2021-02-03|

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EP3791968A1|2021-03-17|

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WO2013131618A8|2015-03-05|

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法律状态:
2018-03-27| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2019-09-10| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2020-10-06| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2020-12-15| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 22/02/2013, OBSERVADAS AS CONDICOES LEGAIS. |

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